Dihydridonitrogen(1+)

Base Information

• Chemical Name: Dihydridonitrogen(1+)
• CAS No.: 14158-23-7
• Molecular Formula: H₃N
• Molecular Weight: 17.0305
• DSSTox Substance ID: DTXSID601315577
• Mol file: 14158-23-7.mol

Synonyms:dihydridonitrogen(1+);Nitrogen, ion (N1+);CHEBI:29338;DTXSID601315577;NH2(+)

Chemical Property of Dihydridonitrogen(1+)

Chemical Property:

• Vapor Pressure: 5990mmHg at 25°C
• XLogP3: -0.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 16.018724068
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: [NH2+]

Technology Process of Dihydridonitrogen(1+)

There total 5 articles about Dihydridonitrogen(1+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-nitrous acid (7782-77-6) → hydroxylammonium + ammonia cation (14158-23-7) + nitrogen (7727-37-9) + dinitrogen monoxide (10024-97-2)

Guidance literature:

{Fe(II)(edta)(H₂O)}^(2-); In water; Electrolysis; controlled potential reduction of aq. soln. on the Hg working electrode at room temp., dependence of the product ratio and the yield on the applied potential and the pH.;

Reference yield:

hydrogen sulfide cation + ammonia (7664-41-7) → ammonia cation (14158-23-7) + mercapto radical (7704-34-9) + hydrogen sulfide (7783-06-4) + Ammonium

Guidance literature:

rate const. determined by ICR and SIFT techniques; Kinetics;

Reference yield:

ammonia (7664-41-7) → NH(1+) (19067-62-0) + ammonia cation (14158-23-7) + nitrenium ion (15194-15-7)

Guidance literature:

In neat (no solvent); ionization of supersonic molecular beam (differentially pumped source, pressure in ionization chamber 3E-8 - 2E-7 Torr); time-of-flight mass spectrometry; estimation of electron-impact cross sections for ionization;

DOI:10.1016/0009-2614(88)87004-0

upstream raw materials:

nitrenium ion

hydrogen sulfide

ammonia

cis-nitrous acid

Downstream raw materials:

sulphonium

mercapto radical

NH₂ radical

ammonia