(3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene

Base Information

Chemical Name:(3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene
CAS No.:142977-24-0
Molecular Formula:C₁₆H₂₂O₃
Molecular Weight:262.349
Hs Code.:

(3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0<sup>3,8</sup>>pentadec-1(15)-ene

Synonyms:(3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene

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Chemical Property of (3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene

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Technology Process of (3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene

There total 1 articles about (3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 556-56-9
allyl iodid

: methyl (1RS)-2,2-<(S,S)-cyclohexane-1,2-dioxy>cyclohexanecarboxylate

: 142977-24-0
(3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene

: 142977-27-3
methyl (1S)-1-allyl-2-<(1S,2S)-2-hydroxycyclohexan-1-yl>oxy-1-methyl-2-cyclohexen-1-carboxylate

: 162489-17-0
methyl (1R)-1-allyl-2-<(1S,2S)-2-hydroxycyclohexan-1-yl>oxy-1-methyl-2-cyclohexen-1-carboxylate

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 - -40 ℃; Yields of byproduct given;
DOI:10.1016/S0040-4020(01)87012-5

Reference yield: 98.0%

: 124-41-4
sodium methylate

: 142977-24-0
(3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene

: 142977-27-3
methyl (1S)-1-allyl-2-<(1S,2S)-2-hydroxycyclohexan-1-yl>oxy-1-methyl-2-cyclohexen-1-carboxylate

Guidance literature:: In methanol; for 48h; Ambient temperature;
DOI:10.1016/S0040-4020(01)87012-5

Reference yield:

: 142977-24-0
(3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene

: 89708-65-6
methyl (R)-1-allyl-2-oxocyclohexanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / methanol

2: 91 percent / BF₃*Et₂O, H₂O / methanol / 60 - 70 °C

With boron trifluoride diethyl etherate; water; In methanol;