89708-65-6

Basic information

• Product Name: Cyclohexanecarboxylic acid, 2-oxo-1-(2-propenyl)-, methyl ester, (R)-
• CAS NO: 89708-65-6
• Molecular Formula: C11H16O3
• Molecular Weight: 196.246
• Mol File: 89708-65-6.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Cyclohexanecarboxylic acid, 2-oxo-1-(2-propenyl)-, methyl ester, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxylic acid, 2-oxo-1-(2-propenyl)-, methyl ester, (R)-(89708-65-6)
• EPA Substance Registry System: Cyclohexanecarboxylic acid, 2-oxo-1-(2-propenyl)-, methyl ester, (R)-(89708-65-6)

Safety Data

• Hazardous Substances Data: 89708-65-6(Hazardous Substances Data)

Upstream product

• 591-87-7 Allyl acetate 
• 41302-34-5 2-(methoxycarbonyl)cyclohexanone 
• 1732-08-7 dimethyl 1,7-heptanedioate 
• 111-16-0 heptanedioic acid 
• 142977-24-0 (3S,8S,11R)-11-allyl-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(15)-ene 
• 142977-18-2 (3S,8S)-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(11)-ene 
• 142977-27-3 methyl (1S)-1-allyl-2-<(1S,2S)-2-hydroxycyclohexan-1-yl>oxy-1-methyl-2-cyclohexen-1-carboxylate 
• 89656-79-1 N-(2-carbomethoxy-1-cyclohexen-1-yl)-(S)-valine tert-butyl ester 
• 106-95-6 allyl bromide 
• 107-18-6 allyl alcohol 
• 556-56-9 allyl iodid 
• 62269-47-0 2-((trimethylsilyl)oxy)cyclohex-1-enecarboxylic acid methyl ester 

Downstream Products

• 94-66-6 2-allylcyclohexan-1-one 
• 51414-47-2 Methyl-2-oxo-3-allylcyclohexancarboxylat 
• 62359-08-4 methyl 1-(2-oxopropyl)-1-cyclohexanecarboxylate 
• 51534-73-7 2-(2-oxocyclohexyl)acetaldehyde 
• 1384423-33-9 3-allyl-1-benzyl-3-fluoroazocane 
• 1384423-27-1 (2-allyl-1-benzylazepan-2-yl)methanol 
• 123532-30-9 1-(propionyloxy)-2-allylcyclohexene 
• 130409-58-4 2-allylcyclohex-1-en-1-yl acetate 
• 94-66-6 (R)-2-allylcyclohexanone 
• 36302-35-9 (S)-2-allylcyclohexanone 
• 138690-59-2 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid 1-allyl-2-oxo-cyclohexylmethyl ester 
• 89100-19-6 1-Allyl-2-oxo-cyclohexanecarboxylic acid 
• 686275-58-1 1,2-diallyl-2-hydroxy-cyclohexanecarboxylic acid methyl ester 
• 686275-59-2 1-allyl-2-but-3-enyl-2-hydroxy-cyclohexanecarboxylic acid methyl ester 

Relevant articles and documents

Atroposelective Synthesis of Axially Chiral N-Arylpyrroles by Chiral-at-Rhodium Catalysis

A transformation of fluxional into configurationally stable axially chiral N-arylpyrroles was achieved with a highly atroposelective electrophilic aromatic substitution catalyzed by a chiral-at-metal rhodium Lewis acid. Specifically, N-arylpyrroles were alkylated with N-acryloyl-1H-pyrazole electrophiles in up to 93 percent yield and with up to >99.5 percent ee, and follow-up conversions reveal the synthetic utility of this new method. DFT calculations elucidate the origins of the observed excellent atroposelectivity.

Ring expansion of cyclic β-amino alcohols induced by diethylaminosulfur trifluoride: Synthesis of cyclic amines with a tertiary fluorine at C3

As the replacement of a hydrogen atom by a fluorine atom in a compound can have an important impact on its biological properties, the development of methods allowing the introduction of a fluorine atom is of great importance. The scope and limitations of

Studies on diastereoselective reduction of cyclic β-ketoesters with boron hydrides. Part 4: The reductive profile of functionalized cyclohexanone derivatives

Reduction of 2-allyl-2-carboalkoxycyclohexanones (3d-f), 2-propyl-2-carboethoxycyclohexanone (3g) and 2-benzyl-2- carboethoxycyclohexanone (3h) with boron hydrides in the presence and absence of several chelating agents were studied. Molecular modeling studies using semiempirical PM3 method were performed in order to find a suitable explanation of the diastereoselection of ketone carbonyl faces during the reductive process, which yielded trans-2-allyl-2-carboethoxycyclohexanol (6e) and cis-2-allyl-2-carboethoxycyclohexanol (7e) in good diastereomeric excess by using inexpensive sodium and tetrabutylammonium borohydrides.