(η4-exo-1-hydro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

Base Information

Chemical Name:(η4-exo-1-hydro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron
CAS No.:112296-18-1
Molecular Formula:C₂₀H₁₆FeO₃Si
Molecular Weight:388.278
Hs Code.:

Synonyms:(η4-exo-1-hydro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

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Chemical Property of (η4-exo-1-hydro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

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Technology Process of (η4-exo-1-hydro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

There total 5 articles about (η4-exo-1-hydro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 16853-85-3
lithium aluminium tetrahydride

: 112296-19-2
(η4-exo-1-chloro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

: 112296-18-1
(η4-exo-1-hydro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

Guidance literature:: In diethyl ether; LiAlH4, Et2O, 0.5 h;
DOI:10.1016/0022-328X(87)85087-8

Reference yield: 66.0%

: 112218-88-9
tricarbonyl(η4-exo-1-methoxy-endo-1-methyl-2,5-diphenylsilole)iron

: 1191-15-7
diisobutylaluminium hydride

: 112296-18-1
(η4-exo-1-hydro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

Guidance literature:: In hexane; soln. of i-Bu2AlH added to soln. of complex (-30°C), mixt. allowed to warm to room temp., stirred for 1h; exclusion of air and moisture; cooled at -78°C;

Reference yield: 66.0%

: 100840-04-8
(η4-1-methoxy-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

: 1191-15-7
diisobutylaluminium hydride

: 112296-18-1
(η4-exo-1-hydro-endo-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

: 100815-46-1
(η4-exo-1-methyl-endo-1-hydro-2,5-diphenylsilacyclopentadiene)tricarbonyliron

Guidance literature:: In hexane; soln. of Fe-compds. cooled to -30°C, addn. of i-Bu2AlH, reaction mixt. allowed to warm to room temp., stirred (1h), filtered, exclusion of air and moisture; cooled to -20°C (yielding endo-methyl isomer), cooled to -78°C (yielding exo-methyl isomer); elem. anal.;