(η4-exo-1-methyl-endo-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron

Base Information

Chemical Name:(η4-exo-1-methyl-endo-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron
CAS No.:112218-89-0
Molecular Formula:C₂₀H₁₅ClFeO₃Si
Molecular Weight:422.723
Hs Code.:

Synonyms:(η4-exo-1-methyl-endo-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron

Suppliers and Price of (η4-exo-1-methyl-endo-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron

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Chemical Property of (η4-exo-1-methyl-endo-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron

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Technology Process of (η4-exo-1-methyl-endo-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron

There total 1 articles about (η4-exo-1-methyl-endo-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 15321-51-4
diiron nonacarbonyl

: 1-chloro-1-methyl-2,5-diphenylsilole

: 112218-89-0,112296-19-2
(η4-1-methyl-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron

Guidance literature:: In toluene; isomer ratio exo:endo = 65:35; fractional crystn. from hexane; elem. anal.;

Reference yield: 90.0%

: 112218-89-0
(η4-exo-1-methyl-endo-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron

: 112295-32-6
(η4-exo-1-methyl-endo-1-methoxy-2,5-diphenylsilacyclopentadiene)tricarbonyliron

Guidance literature:: With methanol; In methanol; MeOH, room temp., 3 h;
DOI:10.1016/0022-328X(87)85087-8

Reference yield: 86.0%

: 67-56-1
methanol

: 112218-89-0,112296-19-2
(η4-1-methyl-1-chloro-2,5-diphenylsilacyclopentadiene)tricarbonyliron

: 100840-04-8
(η4-1-methoxy-1-methyl-2,5-diphenylsilacyclopentadiene)tricarbonyliron

Guidance literature:: In tetrachloromethane; exclusion of air and moisture; addn. of MeOH to soln. of complex (cooled to -20°C), mixt. allowed to warm to room temp., reaction time 3h; isomer ratio endo:exo = 65:35; solvent removed, recrystn. (hexane, -20°C); H-NMR;