3-Butenoic acid, 2-Methyl-, phenylMethyl ester

Base Information

Chemical Name:3-Butenoic acid, 2-Methyl-, phenylMethyl ester
CAS No.:37526-85-5
Molecular Formula:C₁₂H₁₄O₂
Molecular Weight:190.242
Hs Code.:
Mol file:37526-85-5.mol

Synonyms:benzyl 2-methylbut-3-enoate

Suppliers and Price of 3-Butenoic acid, 2-Methyl-, phenylMethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 3-Butenoic acid, 2-Methyl-, phenylMethyl ester

Chemical Property:

Boiling Point:258.9±9.0 °C(Predicted)
Density:1.016±0.06 g/cm3(Predicted)

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-Butenoic acid, 2-Methyl-, phenylMethyl ester

There total 6 articles about 3-Butenoic acid, 2-Methyl-, phenylMethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 53774-20-2
2-methylbut-3-enoic acid

: 100-51-6,185532-71-2
benzyl alcohol

: 37526-85-5
benzyl 2-methylbut-3-enoate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; at 20 ℃; for 12h;
DOI:10.1055/s-2007-977446

Reference yield: 20.0%

: 3017-53-6
benzyl 2-bromopropionate

: 1826-67-1
vinyl magnesium bromide

: 37526-85-5
benzyl 2-methylbut-3-enoate

Guidance literature:: With hexamethylenetetramine; cobalt(II) chloride; (S)-2,2'-bis((S)-4-benzyl-4,5-dihydrooxazol-2-yl)-1,1'-biphenyl; In tetrahydrofuran; at -20 ℃; for 12h; enantioselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.orglett.0c01557

Reference yield:

: 75-16-1
methylmagnesium bromide

: 852402-28-9
4-bromobut-2E-enoic acid benzyl ester

: 37526-85-5
benzyl 2-methylbut-3-enoate

: 121892-75-9
benzyl (E)-pent-2-enoate

Guidance literature:: methylmagnesium bromide; With copper(I) bromide dimethylsulfide complex; (R)-1-[(S_p)-2-(dicyclohexylphosphanyl)ferrocenylethyl]diphenylphosphane; In diethyl ether; dichloromethane; at -78 ℃; Inert atmosphere;

4-bromobut-2E-enoic acid benzyl ester; In diethyl ether; dichloromethane; at -78 ℃; for 16h; regioselective reaction; Inert atmosphere;
DOI:10.1002/adsc.201000109