(-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol

Base Information

Chemical Name:(-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol
CAS No.:283594-56-9
Molecular Formula:C₁₈H₂₇NO₂S
Molecular Weight:321.484
Hs Code.:

Synonyms:(-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol

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Chemical Property of (-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol

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Technology Process of (-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol

There total 2 articles about (-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 78-84-2
isobutyraldehyde

: 167389-29-9
(S)-N-methyl-S-(1-cyclohexen-1-ylmethyl)-S-phenylsulfoximine

: 283594-56-9
(-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol

Guidance literature:: (S)-N-methyl-S-(1-cyclohexen-1-ylmethyl)-S-phenylsulfoximine; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.166667h;

With triisopropoxytitanium(IV) chloride; In diethyl ether; hexane; at -78 - 20 ℃; for 2h;

isobutyraldehyde; In diethyl ether; hexane; at -78 ℃; for 2h;
DOI:10.1002/1099-0690(200012)2000:24<3973::AID-EJOC3973>3.0.CO;2-B

Reference yield: 57.0%

: 78-84-2
isobutyraldehyde

: 167389-29-9
(S)-N-methyl-S-(1-cyclohexen-1-ylmethyl)-S-phenylsulfoximine

: 283594-56-9
(-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol

: 329771-08-6
(+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol

Guidance literature:: (S)-N-methyl-S-(1-cyclohexen-1-ylmethyl)-S-phenylsulfoximine; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.166667h;

With titanium tris(diethylamido)chloride; In diethyl ether; hexane; at -78 - 20 ℃; for 2h;

isobutyraldehyde; In diethyl ether; hexane; at -78 ℃; for 2h;
DOI:10.1002/1099-0690(200012)2000:24<3973::AID-EJOC3973>3.0.CO;2-B

Reference yield: 90.0%

: 283594-56-9
(-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol

: 3019-71-4
Trichloroacetyl isocyanate

: 283594-57-0
(-)-(αS,1R,2Z)-α-(1-methylethyl)-2-{[(S)-N-methyl-S-phenylsulfonimidoyl]methylene}cyclohexylmethyl carbamate

: 573681-68-2
C₂₁H₂₇Cl₃N₂O₄S

Guidance literature:: (-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol; Trichloroacetyl isocyanate; In tetrahydrofuran; at 20 ℃; for 2h;

With ammonium hydroxide; at 20 ℃; for 1h;
DOI:10.1002/ejoc.200390210