(+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol

Base Information

Chemical Name:(+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol
CAS No.:329771-08-6
Molecular Formula:C₁₈H₂₇NO₂S
Molecular Weight:321.484
Hs Code.:

Synonyms:(+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol

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Chemical Property of (+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol

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Technology Process of (+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol

There total 1 articles about (+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 78-84-2
isobutyraldehyde

: 167389-29-9
(S)-N-methyl-S-(1-cyclohexen-1-ylmethyl)-S-phenylsulfoximine

: 283594-56-9
(-)-(Z)-(S)-1-{(R)-2-[(S)-N-methyl-S-phenylsulfonimidoyl]methylenecyclohexyl}-2-methylpropan-1-ol

: 329771-08-6
(+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol

Guidance literature:: (S)-N-methyl-S-(1-cyclohexen-1-ylmethyl)-S-phenylsulfoximine; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.166667h;

With titanium tris(diethylamido)chloride; In diethyl ether; hexane; at -78 - 20 ℃; for 2h;

isobutyraldehyde; In diethyl ether; hexane; at -78 ℃; for 2h;
DOI:10.1002/1099-0690(200012)2000:24<3973::AID-EJOC3973>3.0.CO;2-B

Reference yield: 85.0%

: 50893-53-3
carbonochloridic acid 1-chloro-ethyl ester

: 329771-08-6
(+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol

: 697291-81-9
C₁₀H₁₂ClNO₃S

: (1R,2R)-1-chloro-1-(cyclohex-1-enyl)-3-methylbutan-2-ol

Guidance literature:: In dichloromethane; at 25 ℃; for 2h;
DOI:10.1002/ejoc.200300726

Reference yield:

: 329771-08-6
(+)-(1R,2R)-1-(cyclohex-1-enyl)-1-[(S)-N-methyl-S-phenylsulfonimidoyl]-3-methylbutan-2-ol

: 1193-82-4,4850-71-9,18453-46-8,20696-08-6
(S)-methylphenylsulfoxide

Guidance literature:: Multi-step reaction with 2 steps

1: CH₂Cl₂ / 2 h / 25 °C

2: 85 percent / MeMgCl / tetrahydrofuran / 1 h / -78 °C

With methylmagnesium chloride; In tetrahydrofuran; dichloromethane;
DOI:10.1002/ejoc.200300726