N-(6-Methyl-2,3,4,9-tetrahydro-1H-carbazol-1-ylidene)-1-phenylmethanamine

Base Information

• Chemical Name: N-(6-Methyl-2,3,4,9-tetrahydro-1H-carbazol-1-ylidene)-1-phenylmethanamine
• CAS No.: 115174-30-6
• Molecular Formula: C₂₀H₂₀N₂
• Molecular Weight: 288.392
• Mol file: 115174-30-6.mol

Synonyms:1-benzylimino-6-methyl-1,2,3,4-tetrahydrocarbazole

Chemical Property of N-(6-Methyl-2,3,4,9-tetrahydro-1H-carbazol-1-ylidene)-1-phenylmethanamine

Chemical Property:

Purity/Quality:

98%min ^*data from raw suppliers

N-(6-Methyl-2,3,4,9-tetrahydro-1H-carbazol-1-ylidene)-1-phenylmethanamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(6-Methyl-2,3,4,9-tetrahydro-1H-carbazol-1-ylidene)-1-phenylmethanamine

There total 1 articles about N-(6-Methyl-2,3,4,9-tetrahydro-1H-carbazol-1-ylidene)-1-phenylmethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

6-methyl-2,3,4,9-tetrahydro-1H-carbazol-1-one (3449-48-7,812649-03-9) + benzylamine (100-46-9) → 1-benzylimino-6-methyl-1,2,3,4-tetrahydrocarbazole (115174-30-6)

Guidance literature:

In xylene; for 3h; Heating;

DOI:10.1007/BF00472254

Reference yield: 78.0%

1-benzylimino-6-methyl-1,2,3,4-tetrahydrocarbazole (115174-30-6) + bromoacetic acid methyl ester (96-32-2) → 1-benzylimino-6-methyl-9-carbomethoxymethyl-1,2,3,4-tetrahydrocarbazole (115174-32-8)

Guidance literature:

With sodium hydroxide; In water; benzene; at 25 ℃; for 1h; phase transfer with tetrabutylammonium bromide;

DOI:10.1007/BF00472254

Reference yield:

1-benzylimino-6-methyl-1,2,3,4-tetrahydrocarbazole (115174-30-6) → N-benzyl-6-methyl-2,3,4,9-tetrahydro-1H-carbazol-1-amine (118498-98-9)

Guidance literature:

With sodium tetrahydroborate; In ethanol; at 20 ℃; for 4h;

DOI:10.1007/BF00472254

upstream raw materials:

6-methyl-2,3,4,9-tetrahydro-1H-carbazol-1-one

benzylamine

Downstream raw materials:

N-benzyl-6-methyl-2,3,4,9-tetrahydro-1H-carbazol-1-amine

1-benzylimino-6-methyl-9-carbomethoxymethyl-1,2,3,4-tetrahydrocarbazole

N-benzyl-N-(6-methyl-1,2,3,4-tetrahydro-1-carbazolyl)acetamide

3-benzyl-6-methyl-2-oxo-2,3,3a,4,5,6-hexahydro-1H-pyrazine<3,2,1-j,k>carbazole

Refernces

• 1、 Bokanov, A. I.,Ivanov, P. Yu.,Akalaeva, T. V.,Bogdanova, G. A.,Shvedov, V. I.. "SYNTHESIS OF HETEROCYCLES ON THE BASIS OF IMINOTETRAHYDROCARBAZOLES. 1. 3-BENZYL-8-METHYL-2-OXO-2,3,3a,4,5,6-HEXAHYDRO-1H-PYRAZINOCARBAZOLE". . p. 1311 - 1315. Retrieved 2007/10/02.