2,6-di-O-TBDMS-3,4-di-O-{1-[1(S)-methoxycarbonyl-2-phenylethyl]-4-methyl-1H-1,2,3-triazol-4-yl}-β-D-glucopyranosyl 1,4-dimethoxynaphthalene

Base Information

Chemical Name:2,6-di-O-TBDMS-3,4-di-O-{1-[1(S)-methoxycarbonyl-2-phenylethyl]-4-methyl-1H-1,2,3-triazol-4-yl}-β-D-glucopyranosyl 1,4-dimethoxynaphthalene
CAS No.:1353897-38-7
Molecular Formula:C₅₆H₇₆N₆O₁₁Si₂
Molecular Weight:1065.42
Hs Code.:

Synonyms:2,6-di-O-TBDMS-3,4-di-O-{1-[1(S)-methoxycarbonyl-2-phenylethyl]-4-methyl-1H-1,2,3-triazol-4-yl}-β-D-glucopyranosyl 1,4-dimethoxynaphthalene

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Chemical Property of 2,6-di-O-TBDMS-3,4-di-O-{1-[1(S)-methoxycarbonyl-2-phenylethyl]-4-methyl-1H-1,2,3-triazol-4-yl}-β-D-glucopyranosyl 1,4-dimethoxynaphthalene

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Technology Process of 2,6-di-O-TBDMS-3,4-di-O-{1-[1(S)-methoxycarbonyl-2-phenylethyl]-4-methyl-1H-1,2,3-triazol-4-yl}-β-D-glucopyranosyl 1,4-dimethoxynaphthalene

There total 4 articles about 2,6-di-O-TBDMS-3,4-di-O-{1-[1(S)-methoxycarbonyl-2-phenylethyl]-4-methyl-1H-1,2,3-triazol-4-yl}-β-D-glucopyranosyl 1,4-dimethoxynaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.2%

: 1353897-37-6
3,4-di-O-propynyl-2,6-O-TBDMS-C-glucosyl 1,4-dimethoxynaphthalene

: 116911-32-1
(S)-2-azido-3-phenylpropionic acid methyl ester

: 1353897-38-7
2,6-di-O-TBDMS-3,4-di-O-{1-[1(S)-methoxycarbonyl-2-phenylethyl]-4-methyl-1H-1,2,3-triazol-4-yl}-β-D-glucopyranosyl 1,4-dimethoxynaphthalene

Guidance literature:: With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In dichloromethane; water; at 20 ℃; for 12h;
DOI:10.1039/c1ob06242e

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1353897-38-7
2,6-di-O-TBDMS-3,4-di-O-{1-[1(S)-methoxycarbonyl-2-phenylethyl]-4-methyl-1H-1,2,3-triazol-4-yl}-β-D-glucopyranosyl 1,4-dimethoxynaphthalene

Guidance literature:: Multi-step reaction with 3 steps

1: dmap / pyridine

2: sodium hydride / N,N-dimethyl-formamide

3: copper(ll) sulfate pentahydrate; sodium L-ascorbate / dichloromethane; water / 12 h / 20 °C

With dmap; copper(ll) sulfate pentahydrate; sodium hydride; sodium L-ascorbate; In pyridine; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1039/c1ob06242e

Reference yield:

: 915716-23-3
2-(β-D-glucopyranosyl)-1,4-dimethoxynaphthalene

: 1353897-38-7
2,6-di-O-TBDMS-3,4-di-O-{1-[1(S)-methoxycarbonyl-2-phenylethyl]-4-methyl-1H-1,2,3-triazol-4-yl}-β-D-glucopyranosyl 1,4-dimethoxynaphthalene

Guidance literature:: Multi-step reaction with 3 steps

1: dmap / pyridine

2: sodium hydride / N,N-dimethyl-formamide

3: copper(ll) sulfate pentahydrate; sodium L-ascorbate / dichloromethane; water / 12 h / 20 °C

With dmap; copper(ll) sulfate pentahydrate; sodium hydride; sodium L-ascorbate; In pyridine; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1039/c1ob06242e