(4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol

Base Information

Chemical Name:(4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol
CAS No.:1227476-21-2
Molecular Formula:C₂₂H₃₈O₄Si
Molecular Weight:394.627
Hs Code.:

Synonyms:(4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol

Suppliers and Price of (4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol

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Technology Process of (4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol

There total 1 articles about (4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 24850-33-7
allyltributylstanane

: 325172-30-3
(S)-3-((tert-butyldimethylsilyl)oxy)-5-((4-methoxybenzyl)oxy)pentanal

: 1227476-21-2
(4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol

Guidance literature:: With (R)-1,1'-Bi-2-naphthol; titanium(IV)isopropoxide; In dichloromethane; at -78 - -20 ℃; for 12h; Molecular sieve;
DOI:10.1016/j.tetlet.2010.02.133

Reference yield: 90.0%

: 1227476-21-2
(4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1227476-22-3
(5R,7S)-5-allyl-2-(4-methoxybenzyloxy)ethyl-2,2,3,3,9,9,10,10-octamethyl-4,8-dioxa-3,9-disilaundecane

Guidance literature:: (4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol; With 1H-imidazole; In dichloromethane; at 0 ℃; for 0.166667h;

tert-butyldimethylsilyl chloride; With dmap; In dichloromethane; for 3h;
DOI:10.1016/j.tetlet.2010.02.133

Reference yield: 85.0%

: 1227476-21-2
(4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol

: 77-76-9
2,2-dimethoxy-propane

: 1227476-25-6
C₁₉H₂₈O₄

Guidance literature:: (4R,6S)-6-(tert-butyldimethylsilyloxy)-8-(4-methoxybenzyloxy)oct-1-en-4-ol; With pyridine hydrogenfluoride; In tetrahydrofuran; at 0 - 20 ℃; for 12h;

2,2-dimethoxy-propane; With pyridinium p-toluenesulfonate; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1016/j.tetlet.2010.02.133