1,3,5-Undecatriene, (E,Z)-

Base Information

• Chemical Name: 1,3,5-Undecatriene, (E,Z)-
• CAS No.: 51447-08-6
• Molecular Formula: C11H18
• Molecular Weight: 150.264
• European Community (EC) Number: 257-214-4
• UNII: 1Z505W410B
• Wikidata: Q27253282
• Metabolomics Workbench ID: 170449
• Mol file: 51447-08-6.mol

Synonyms:(3Z,5E)-1,3,5-Undecatriene;1,3,5-Undecatriene, (E,Z)-;1,3,5-Undecatriene, (3Z,5E)-;UNII-1Z505W410B;(E,Z)-Undeca-1,3,5-triene;1,3,5-Undecatriene, (Z,E)-;EINECS 257-214-4;1Z505W410B;51447-08-6;cis,trans-1,3,5-Undecatriene;C11-H18;JQQDKNVOSLONRS-BABZSUFTSA-N;AKOS024263056;Q27253282

Chemical Property of 1,3,5-Undecatriene, (E,Z)-

Chemical Property:

• Boiling Point: 206.7°Cat760mmHg
• Flash Point: 65.8°C
• PSA: 0.00000
• Density: 0.78g/cm³
• LogP: 3.86510
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 150.140850574
• Heavy Atom Count: 11
• Complexity: 129

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC=CC=CC=C
• Isomeric SMILES: CCCCC/C=C/C=C\C=C

Technology Process of 1,3,5-Undecatriene, (E,Z)-

There total 69 articles about 1,3,5-Undecatriene, (E,Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

trans,trans-2,4-decadienal (25152-84-5,65909-91-3) + Methyltriphenylphosphonium bromide (1779-49-3) → (3E,5E)-1,3,5-undecatriene (16356-11-9,19883-26-2,19883-27-3,51447-08-6,151123-08-9,19883-29-5)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2010.01.066

Reference yield: 90.0%

vinyl magnesium bromide (1826-67-1) + (E,E)-1-chloro-1,3-nonadiene (111649-77-5) → (3E,5E)-1,3,5-undecatriene (16356-11-9,19883-26-2,19883-27-3,51447-08-6,151123-08-9,19883-29-5)

Guidance literature:

tetrakis(triphenylphosphine)nickel⁽⁰⁾; In tetrahydrofuran; diethyl ether; benzene; at 20 ℃; for 1.5h;

Reference yield: 90.0%

trans,trans-2,4-decadienal (25152-84-5,65909-91-3) + Methylenetriphenylphosphorane (19493-09-5) → (3E,5E)-1,3,5-undecatriene (16356-11-9,19883-26-2,19883-27-3,51447-08-6,151123-08-9,19883-29-5)

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1016/S0040-4039(00)73742-7

upstream raw materials:

undeca-1,2,4c-triene

pyridazinyl-N-oxide

(Z)-hept-1-enylmagnesium bromide

(E)-1,5-undecadien-3-yne

Downstream raw materials:

5-pentyl-cyclohexa-1,3-diene

3-((E)-Hept-1-enyl)-4-((1E,3E)-nona-1,3-dienyl)-cyclohexene

N,N'-((2E,4E)-undeca-2,4-diene-1,6-diyl)bis(4-methyl-N-tosylbenzenesulfonamide)