(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

Base Information

Chemical Name:(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane
CAS No.:165960-99-6
Molecular Formula:C₂₈H₅₂O₄Si
Molecular Weight:480.804
Hs Code.:

Synonyms:(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

Suppliers and Price of (+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

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Technology Process of (+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

There total 3 articles about (+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 165960-98-5
(R)-13-Benzyloxy-4-methoxymethoxy-tridecan-1-ol

: 165960-99-6
(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

Guidance literature:: With 1H-imidazole; triethylamine; In dichloromethane; for 18h; Ambient temperature;
DOI:10.1021/jo00119a019

Reference yield:

: 165960-97-4
((R)-10-Methoxymethoxy-tridec-12-enyloxymethyl)-benzene

: 165960-99-6
(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) BH₃*THF, 2.) aq. NaOH, 30percent aq. H₂O₂ / 1.) THF, room temp., 12 h, 2.) room temp., 1 h

2: 99 percent / Et₃N, imidazole / CH₂Cl₂ / 18 h / Ambient temperature

With 1H-imidazole; sodium hydroxide; borane-THF; dihydrogen peroxide; triethylamine; In dichloromethane;
DOI:10.1021/jo00119a019

Reference yield:

: 13-(Benzyloxy)-4-hydroxy-1-tridecene

: 165960-99-6
(+)-(4R)-13-(Benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-4-<(methoxymethyl)oxy>tridecane

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / i-Pr₂NEt / CH₂Cl₂ / 17 h / Ambient temperature

2: 1.) BH₃*THF, 2.) aq. NaOH, 30percent aq. H₂O₂ / 1.) THF, room temp., 12 h, 2.) room temp., 1 h

3: 99 percent / Et₃N, imidazole / CH₂Cl₂ / 18 h / Ambient temperature

With 1H-imidazole; sodium hydroxide; borane-THF; dihydrogen peroxide; triethylamine; N-ethyl-N,N-diisopropylamine; In dichloromethane;
DOI:10.1021/jo00119a019