(1R,2R,3S,4S)-3-benzyloxycarbonylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

Base Information

Chemical Name:(1R,2R,3S,4S)-3-benzyloxycarbonylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester
CAS No.:1071520-16-5
Molecular Formula:C₁₇H₁₉NO₄
Molecular Weight:301.342
Hs Code.:

Synonyms:(1R,2R,3S,4S)-3-benzyloxycarbonylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

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Chemical Property of (1R,2R,3S,4S)-3-benzyloxycarbonylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

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Technology Process of (1R,2R,3S,4S)-3-benzyloxycarbonylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

There total 5 articles about (1R,2R,3S,4S)-3-benzyloxycarbonylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 131433-32-4
(2S,3R)-3-exo-methoxycarbonyl-bicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

: 100-51-6,185532-71-2
benzyl alcohol

: 1071520-16-5
(1R,2R,3S,4S)-3-benzyloxycarbonylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

Guidance literature:: (2S,3R)-3-exo-methoxycarbonyl-bicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid; With chloroformic acid ethyl ester; triethylamine; In tetrahydrofuran; at 0 ℃; Inert atmosphere;

With sodium azide; In tetrahydrofuran; water; at 0 - 25 ℃;

benzyl alcohol;

Reference yield:

: 541-41-3
chloroformic acid ethyl ester

: 131433-32-4
(2S,3R)-3-exo-methoxycarbonyl-bicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

: 100-51-6,185532-71-2
benzyl alcohol

: 1071520-16-5
(1R,2R,3S,4S)-3-benzyloxycarbonylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

Guidance literature:: chloroformic acid ethyl ester; (2S,3R)-3-exo-methoxycarbonyl-bicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid; With triethylamine; In tetrahydrofuran; at 0 ℃; Inert atmosphere;

With sodium azide; In tetrahydrofuran; water; at 0 - 25 ℃;

benzyl alcohol; With triethylamine; In dichloromethane; for 16h; Reflux; Inert atmosphere;

Reference yield:

: C₉H₁₁N₃O₂

: 100-51-6,185532-71-2
benzyl alcohol

: 1071520-16-5
(1R,2R,3S,4S)-3-benzyloxycarbonylamino-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester

Guidance literature:: C₉H₁₁N₃O₂; In benzene; for 2h; Heating / reflux;

benzyl alcohol; With triethylamine; In dichloromethane; for 16h; Heating / reflux;