Trimethyl[(phenylthio)(tributylstannyl)methyl]silane

Base Information

• Chemical Name: Trimethyl[(phenylthio)(tributylstannyl)methyl]silane
• CAS No.: 79409-19-1
• Molecular Formula: C₂₂H₄₂SSiSn
• Molecular Weight: 485.437
• Mol file: 79409-19-1.mol

Synonyms:(phenylthio)(tri-n-butylstannyl)(trimethylsilyl)methane

Chemical Property of Trimethyl[(phenylthio)(tributylstannyl)methyl]silane

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of Trimethyl[(phenylthio)(tributylstannyl)methyl]silane

There total 1 articles about Trimethyl[(phenylthio)(tributylstannyl)methyl]silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(phenylsulfanylmethyl)trimethylsilane (17873-08-4) + tributyltin chloride (1461-22-9) → (phenylthio)(tri-n-butylstannyl)(trimethylsilyl)methane (79409-19-1)

Guidance literature:

With n-butyllithium; ammonium chloride; In tetrahydrofuran; hexane; N2-atmosphere; stirring of sulfur compd. with BuLi (0.5 h), addn. of Bu3SnCl, warming to room temp. (overnight); pouring into satd. aq. NH4Cl, washing (satd. aq. NaCl), drying (Na2SO4), evapn. (reduced pressure), chromy. (SiO2, petroleum ether); elem. anal.;

DOI:10.1021/om00140a026

Reference yield: 70.0%

1-(Trimethylsilyloxy)cyclohexene (6651-36-1) + (phenylthio)(tri-n-butylstannyl)(trimethylsilyl)methane (79409-19-1) → 2-<(phenylthio)trimethylsilylmethyl>cyclohexanone (82202-15-1)

Guidance literature:

With 4 A molecular sieve; tetrabutylammonium tetrafluoroborate; potassium carbonate; In dichloromethane; electrochemical reaction: in a divided cell equipped with a carbon felt anode, platinum plate cathode or an undivided cell equipped with a carbon rod anode, platinum plate cathode;

DOI:10.1246/cl.1998.1011

Reference yield: 64.0%

benzaldehyde (100-52-7) + (phenylthio)(tri-n-butylstannyl)(trimethylsilyl)methane (79409-19-1) → phenyl(styryl)sulfane (7214-56-4) + (E)-[2-(phenylsulfanyl)vinyl]benzene (7214-53-1) + 1-phenyl-2-phenylsulfanyl-ethanol (67210-34-8,67210-39-3,121053-49-4,16162-51-9) + 1-phenyl-2-phenylsulfanyl-2-tributylstannanyl-ethanol + tributyl[(phenylsulfanyl)methyl]stannane (34694-32-1)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at -78 - 20 ℃; for 13h; Temperature; Molecular sieve; Inert atmosphere;

DOI:10.24820/ark.5550190.p011.038

upstream raw materials:

(phenylsulfanylmethyl)trimethylsilane

tributyltin chloride

Downstream raw materials:

2-<(phenylthio)trimethylsilylmethyl>cyclohexanone

2,2-diphenyl-1-(tri-n-butylstannyl)-1-(phenylthio)ethene

1-(tri-n-butylstannyl)-1-(phenylthio)-2-phenylethene

phenyl(styryl)sulfane

Refernces