7214-56-4

Basic information

• Product Name: Benzene, [(2-phenylethenyl)thio]-, (Z)-
• CAS NO: 7214-56-4
• Molecular Formula: C14H12S
• Molecular Weight: 212.315
• Mol File: 7214-56-4.mol
• Article Data: 73

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-phenylethenyl)thio]-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-phenylethenyl)thio]-, (Z)-(7214-56-4)
• EPA Substance Registry System: Benzene, [(2-phenylethenyl)thio]-, (Z)-(7214-56-4)

Safety Data

• Hazardous Substances Data: 7214-56-4(Hazardous Substances Data)

Upstream product

• 588-73-8 (Z)-β-bromostyrene 
• 108-98-5 thiophenol 
• 15799-66-3 trans-β-triphenylstannylstyrene 
• 100-52-7 benzaldehyde 
• 178321-37-4 Phenylsulfanylmethyl-phosphonic acid bis-(2,2,2-trifluoro-ethyl) ester 
• 16212-06-9 phenyl styryl sulfone 
• 42599-24-6 E-styryl iodide 
• 38066-16-9 diethyl [(phenylthio)methyl]phosphonate 
• 882-33-7 diphenyldisulfane 
• 102-96-5 (2-nitroethenyl)benzene 
• 637-44-5 phenylpropyolic acid 
• 622-25-3 1-(2-chlorovinyl)benzene 
• 536-74-3 phenylacetylene 
• 515-42-4 sodium phenylsulfonate 

Downstream Products

• 645-49-8 cis-stilben 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 7214-53-1 (E)-[2-(phenylsulfanyl)vinyl]benzene 
• 134996-34-2 (Z)-3-phenyl-2-(phenylmercapto)-2-propenyl alcohol 
• 98496-59-4 1-((Z)-2-Benzenesulfonyl-1-phenyl-ethenesulfonyl)-4-bromo-benzene 
• 98496-58-3 1-((Z)-2-Benzenesulfonyl-1-phenyl-ethenesulfonyl)-4-chloro-benzene 
• 98496-57-2 1-((Z)-2-Benzenesulfonyl-1-phenyl-ethenesulfonyl)-4-methyl-benzene 
• 98496-56-1 (Z)-α,β-bis(phenylsulfonyl)styrene 
• 98496-55-0 2-((Z)-2-Benzenesulfonyl-1-phenyl-vinylsulfanyl)-phenylamine 
• 98496-49-2 1-((Z)-2-Benzenesulfonyl-1-phenyl-vinylsulfanyl)-4-bromo-benzene 
• 98496-48-1 1-((Z)-2-Benzenesulfonyl-1-phenyl-vinylsulfanyl)-4-chloro-benzene 
• 98496-47-0 1-((Z)-2-Benzenesulfonyl-1-phenyl-vinylsulfanyl)-4-methyl-benzene 
• 98496-46-9 C₂₀H₁₆O₂S₂ 
• 52920-46-4 Z-2-bromo-2-phenyl-1-(phenylsulfonyl)ethene 

Relevant articles and documents

Continuous Flow Sodiation of Substituted Acrylonitriles, Alkenyl Sulfides and Acrylates

The sodiation of substituted acrylonitriles and alkenyl sulfides in a continuous flow set-up using NaDA (sodium diisopropylamide) in EtNMe2 or NaTMP (sodium 2,2,6,6-tetramethylpiperidide)?TMEDA in n-hexane provides sodiated acrylonitriles and alkenyl sulfides, which are subsequently trapped in batch with various electrophiles such as aldehydes, ketones, disulfides and allylic bromides affording functionalized acrylonitriles and alkenyl sulfides. This flow-procedure was successfully extended to other acrylates by using Barbier-type conditions.

Catalytic conversion of alkynes to α-vinyl sulfides mediated by carbene-linker-carbene (CXC) rhodium and iridium complexes

The catalytic activity of a set of mono- and bimetallic Rh(i) and Ir(i) complexes bearing carbene-linker-carbene (CXC) bis-triazolylidene ligands (with X = O, N) coordinated in a bridging or chelating fashion was evaluated in the hydrothiolation of alkyne

Facile Thiol–Ene Click Protocol Using Benzil as Sensitizer and White LED as Light Source

The thiol–ene reaction leading to a series of thioether derivatives by simple metal and oxidant free visible light promoted photosensitized protocol, following anti-Markonikov hydrothiolation of unactivated aryl and alkyl olefins at room temperature is demonstrated. Benzil served as a green photosensitizer in this reaction and white LED lights as a light source. This radical based thiol–ene reaction is operationally simple and tolerates a wide variety of functional groups present in olefins.