7214-53-1

Basic information

• Product Name: Benzene, [[(1E)-2-phenylethenyl]thio]-
• CAS NO: 7214-53-1
• Molecular Formula: C14H12S
• Molecular Weight: 212.315
• Mol File: 7214-53-1.mol
• Article Data: 114

Chemical Properties

• CAS DataBase Reference: Benzene, [[(1E)-2-phenylethenyl]thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(1E)-2-phenylethenyl]thio]-(7214-53-1)
• EPA Substance Registry System: Benzene, [[(1E)-2-phenylethenyl]thio]-(7214-53-1)

Safety Data

• Hazardous Substances Data: 7214-53-1(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 536-74-3 phenylacetylene 
• 588-73-8 (Z)-β-bromostyrene 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 17314-33-9 tributyltin phenyl sulfide 
• 103-64-0 bromostyrene 
• 930-69-8 sodium thiophenolate 
• 7214-56-4 phenyl(styryl)sulfane 
• 13865-49-1 [2-(phenylsulfanyl)ethyl]benzene 
• 17101-82-5 E-β-bromovinyl phenyl sulfide 
• 100-58-3 phenylmagnesium bromide 
• 77086-38-5 ketene t-butyldimethylsilyl methyl acetal 
• 7205-91-6 phenylthiomethyl chloride 
• 140-29-4 phenylacetonitrile 

Downstream Products

• 3846-66-0 β-tert-butylstyrene 
• 113303-14-3 3,3-dimethyl-2-phenylbutyl phenyl sulfide 
• 113303-15-4 3,3-dimethyl-2-phenyl-1-butenyl phenyl sulfide 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 98750-73-3 C₁₄H₁₂Cl₂S 
• 40110-66-5 (E)-2-phenyl-1-(phenylsulfinyl)ethene 
• 139-66-2 diphenyl sulfide 
• 106895-97-0 1-phenyl-1-<2-(phenylthio)phenyl>ethene 
• 20442-73-3 (1E)-3-(4-methoxyphenyl)-1-phenylpropene 
• 21502-38-5 (1E,4E)-1-phenyl-1,4-hexadiene 
• 109898-19-3 (E)-(3-methylpenta-1,4-dien-1-yl)benzene 
• 55666-17-6 (1E)-1,4-pentadienylbenzene 
• 886-65-7 trans,trans-1,4-Diphenyl-1,3-butadiene 
• 3412-44-0 (1E)-1,3-diphenylpropene 

Relevant articles and documents

Method for preparing aryl vinyl alkyl thioether through C/C-S monatomic assembly process

The invention discloses a method for preparing aryl vinyl alkyl thioether through a C = C-S monatomic assembly process, which comprises the following steps: respectively providing an atom for a C = C-S structure by dimethyl sulfoxide, aromatic aldehyde ketone and sulfur-containing reagent sodium mercaptide/dithioether under the action of air atmosphere and alkali; the construction process is completed by one-pot reaction, and the product aryl vinyl alkyl thioether compound is obtained. The aryl vinyl of the aryl vinyl alkyl thioether compound prepared by the method comes from aromatic aldehyde ketone, but a double-bond carbon atom is added compared with the original aromatic aldehyde ketone raw material, and the method has the advantages of wide and easily available raw material source, environmental protection, low price, simple operation and facilitation of industrial production.

Catalytic conversion of alkynes to α-vinyl sulfides mediated by carbene-linker-carbene (CXC) rhodium and iridium complexes

The catalytic activity of a set of mono- and bimetallic Rh(i) and Ir(i) complexes bearing carbene-linker-carbene (CXC) bis-triazolylidene ligands (with X = O, N) coordinated in a bridging or chelating fashion was evaluated in the hydrothiolation of alkyne

Sulfur?oxygen interaction-controlled (Z)-selectiveanti-Markovnikov vinyl sulfides

The sulfur oxygen (S?O) interaction was used herein to obtain (Z)-selectiveanti-Markovnikov vinyl sulfides from the addition of thiyl radicals to terminal alkynes. DFT calculations predicted that S?O interaction originated from the delocalization of the lone-pair of the carbonyl oxygen to the adjacent σ* orbital of the S atom of C-S.