[2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone

Base Information

Chemical Name:[2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone
CAS No.:1320259-68-4
Molecular Formula:C₂₉H₃₃ClO₉
Molecular Weight:561.029
Hs Code.:

Synonyms:[2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone

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Chemical Property of [2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone

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Technology Process of [2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone

There total 12 articles about [2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1320259-67-3
2,6-bis(methoxymethoxy)-α-[3-chloro-4-methoxy-2-methoxymethoxy-6-[(phenylmethoxy)-methyl]]-4-methyl-benzenemethanol

: 1320259-68-4
[2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 25 ℃; for 3.5h; Inert atmosphere;
DOI:10.1021/ol201561w

Reference yield:

: C₁₇H₁₃ClO₇

: 1320259-68-4
[2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone

: methyl 9-chloro-1-hydroxy-8-methoxy-3-methyl-11-oxo-1H-dibenzo-[b,e][1,4]-dioxepine-6-carboxylate

Guidance literature:: C₁₇H₁₃ClO₇; With potassium hexacyanoferrate(III); In water; tert-butyl alcohol; at 0 ℃; Inert atmosphere;

With sulfuric acid; In water; tert-butyl alcohol; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/ol201561w

Reference yield:

: 1320259-65-1
3-chloro-4-methoxy-2-methoxymethoxy6-[(phenylmethoxy)methyl]-benzaldehyde

: 1320259-68-4
[2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.33 h / 0 - 25 °C / Inert atmosphere

1.2: 4 h / 0 - 25 °C / Inert atmosphere

2.1: Dess-Martin periodane / dichloromethane / 3.5 h / 25 °C / Inert atmosphere

With n-butyllithium; Dess-Martin periodane; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ol201561w