Pentaerythritol tetraacrylate

Base Information

• Chemical Name: Pentaerythritol tetraacrylate
• CAS No.: 4986-89-4
• Deprecated CAS: 113674-04-7,124538-16-5,150315-46-1,152992-37-5,154303-16-9,93218-05-4,255831-13-1,1036032-39-9,2133837-86-0,2629929-21-9,124538-16-5,150315-46-1,152992-37-5,154303-16-9,255831-13-1,93218-05-4
• Molecular Formula: C17H20 O8
• Molecular Weight: 352.341
• Hs Code.: 29161290
• European Community (EC) Number: 225-644-1
• UNII: 50LIA3DGN1
• DSSTox Substance ID: DTXSID8042264
• Nikkaji Number: J60.756H
• Wikipedia: Pentaerythritol_tetraacrylate
• Wikidata: Q27260804
• ChEMBL ID: CHEMBL3188166
• Mol file: 4986-89-4.mol

Synonyms:2-Propenoicacid, 2,2-bis[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester (9CI);Acrylic acid, neopentanetetrayl ester (7CI); Acrylic acid, tetraester withpentaerythritol (8CI); A-TMMT; Aronix M 450; BS 710; Beam Set 710; KayaradA-TMMT; Kayarad PET 40; Kayarad SR 295; Light Acrylate PE 4A; M 450; NK EsterA-TMMT; NK Ester A-YMMT; Pentaerythritol tetraacrylate; Pentaerythritoltetracrylate; SR 295; SR 295 (acrylate); Saret SR 295; Sartomer 295; SartomerSR 295; Tetramethylolmethane tetraacrylate; Tetramethylolmethane tetracrylate;Viscoat 400

Chemical Property of Pentaerythritol tetraacrylate

Chemical Property:

• Melting Point: 18ºC
• Refractive Index: n20/D 1.487(lit.)
• Boiling Point: 450.3 ºC at 760 mmHg
• Flash Point: 196 ºC
• PSA: 105.20000
• Density: 1.16 g/cm³
• LogP: 0.88960
• Storage Temp.: Amber Vial, Refrigerator, Under inert atmosphere
• Solubility.: Chloroform, Methanol (Sparingly)
• XLogP3: 2.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 16
• Exact Mass: 352.11581759
• Heavy Atom Count: 25
• Complexity: 460

Purity/Quality:

99% ^*data from raw suppliers

PentaerythritolTetraacrylate(~80%) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/38-43
• Safety Statements: 26-39-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C
• Uses: PENTAERYTHRITOL TETRAACRYLATE is a useful research chemical. PETA can be used in the synthesis of gel polymer electrolyte for the fabrication of lithium-sulfur batteries.

Technology Process of Pentaerythritol tetraacrylate

There total 11 articles about Pentaerythritol tetraacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.6%

Pentaerythritol (115-77-5) + acryloyl chloride (814-68-6,25189-84-8) → pentaerythritol tetraacrylate (4986-89-4)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 2.5h;

DOI:10.1021/ma301849a

Reference yield:

Pentaerythritol (115-77-5) + acrylic acid (79-10-7) → pentaerythritol tetraacrylate (4986-89-4)

Guidance literature:

With methanesulfonic acid; hypophosphorous acid; copper(l) chloride; In toluene; at 70 ℃; Inert atmosphere;

Reference yield:

Pentaerythritol (115-77-5) + acetic anhydride (108-24-7) + acrylic acid (79-10-7) → Pentaerithrit-triacetat-acrylat (51690-75-6) + C15H20O8 + C16H20O8 + pentaerythritol tetraacrylate (4986-89-4)

Guidance literature:

Pentaerythritol; acrylic acid; With methanesulfonic acid; 4-methoxy-phenol; copper(l) chloride; In water; toluene; at 75 ℃; for 15h; under 1125.11 Torr; Inert atmosphere;

acetic anhydride; With methanesulfonic acid; 4-methoxy-phenol; In toluene; at 35 - 40 ℃; for 1h; Inert atmosphere;

upstream raw materials:

(E)-but-2-enol

Pentaerythritol

4-methoxy-phenol

acrylic acid

Downstream raw materials:

C₃₂H₃₉NO₉

C₃₅H₄₁NO₁₀

C₅₀H₆₀N₂O₁₁

C₅₃H₆₂N₂O₁₂

Refernces

• 1、 -. "Carbonated polyols and acrylate-based compound thereof". Paragraph 0091-0093. . Retrieved 2019/08/01.
• 2、 -. "Modified acrylate, preparation method thereof and application of modified acrylate in preparation of conductive adhesive". Paragraph 0072-0077. . Retrieved 2019/11/28.