11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile

Base Information

Chemical Name:11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile
CAS No.:84574-16-3
Molecular Formula:C₃₁H₄₁NO₆S
Molecular Weight:555.736
Hs Code.:

11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile

Synonyms:11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile

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Chemical Property of 11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile

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Technology Process of 11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile

There total 11 articles about 11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 84574-15-2
2-[6-Cyano-6-(1-ethoxy-ethoxy)-1-phenylsulfanyl-hexyl]-4,6-dimethoxy-benzoic acid 4-iodo-1-methyl-butyl ester

: 84574-16-3
11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile

Guidance literature:: With sodium hexamethyldisilazane; In tetrahydrofuran; at 40 ℃; for 0.5h; reverse addition method;
DOI:10.1016/S0040-4039(00)85600-2

Reference yield: 82.0%

: 84597-65-9
2,4-Dimethoxy-6-[1-phenylsulfanyl-5-(toluene-4-sulfonyloxy)-pentyl]-benzoic acid 5-cyano-5-(1-ethoxy-ethoxy)-1-methyl-pentyl ester

: 84574-16-3
11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile

Guidance literature:: With sodium hexamethyldisilazane; In tetrahydrofuran; at 40 ℃; for 0.5h;
DOI:10.1016/S0040-4039(00)85600-2

Reference yield:

: 15146-94-8
5-chloro-2-pentanol

: 84574-16-3
11-(1-Ethoxy-ethoxy)-2,4-dimethoxy-7-methyl-5-oxo-16-phenylsulfanyl-7,8,9,10,11,12,13,14,15,16-decahydro-5H-6-oxa-benzocyclotetradecene-11-carbonitrile

Guidance literature:: Multi-step reaction with 8 steps

1: Pd

2: KN(SiMe₃)2

3: KI / hexamethylphosphoric acid triamide

4: H₂O, H⁽¹⁺⁾

5: CrO₃, pyridine

6: NaHSO₃

7: H₃O⁽¹⁺⁾

8: 95 percent / NaN(SiMe₃)2 / tetrahydrofuran / 0.5 h / 40 °C / reverse addition method

With pyridine; chromium(VI) oxide; oxonium; water; sodium hexamethyldisilazane; hydrogen cation; potassium hexamethylsilazane; sodium hydrogensulfite; potassium iodide; palladium; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide;
DOI:10.1016/S0040-4039(00)85600-2