[dichlorobis(2-tert-butyl-6-methylphenolate)titanium(IV)]

Base Information

• Chemical Name: [dichlorobis(2-tert-butyl-6-methylphenolate)titanium(IV)]
• CAS No.: 229467-43-0
• Molecular Formula: C₂₂H₃₀Cl₂O₂Ti
• Molecular Weight: 445.265
• Mol file: 229467-43-0.mol

Synonyms:[dichlorobis(2-tert-butyl-6-methylphenolate)titanium(IV)]

Chemical Property of [dichlorobis(2-tert-butyl-6-methylphenolate)titanium(IV)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [dichlorobis(2-tert-butyl-6-methylphenolate)titanium(IV)]

There total 4 articles about [dichlorobis(2-tert-butyl-6-methylphenolate)titanium(IV)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2-tert-Butyl-6-methylphenol (2219-82-1) + titanium tetrachloride (7550-45-0) → [dichlorobis(2-tert-butyl-6-methylphenolate)titanium(IV)] (229467-43-0)

Guidance literature:

In toluene; byproducts: HCl; N2, vigorously refluxed for 18 h; cooled, filtered, solvent removed; elem. anal.;

DOI:10.1002/ejic.200400769

Reference yield: 42.0%

tetrachlorosilane (10026-04-7,53609-55-5) + (2-tert-butyl-6-methylphenyl-O)2Ti(NEt2)2 (229467-42-9) → [dichlorobis(2-tert-butyl-6-methylphenolate)titanium(IV)] (229467-43-0)

Guidance literature:

In toluene; inert atmosphere; 10 equivs. of SiCl4, stirring at 23°C for 3 h; evapn., recrystn. (MePh:hexanes, -35°C);

DOI:10.1021/om9808099

Reference yield:

2-tert-Butyl-6-methylphenol (2219-82-1) → [dichlorobis(2-tert-butyl-6-methylphenolate)titanium(IV)] (229467-43-0)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: toluene

In toluene;

DOI:10.1021/om9808099

upstream raw materials:

2-tert-Butyl-6-methylphenol

titanium tetrachloride

tetrachlorosilane

(2-tert-butyl-6-methylphenyl-O)2Ti(NEt₂)2

Downstream raw materials:

(2-tert-butyl-6-methylphenyl-O)2TiBr₂

(2-tert-butyl-6-methylphenyl-O)2TiI₂

[dichlorobis(2-tert-butyl-6-methylphenolate)(4,4'-dimethyl-2,2'-bipyridine)titanium(IV)]