1,1,2,3-Tetrachloropropene

Base Information

• Chemical Name: 1,1,2,3-Tetrachloropropene
• CAS No.: 10436-39-2
• Molecular Formula: C3H2 Cl4
• Molecular Weight: 179.861
• Hs Code.: 29333999
• European Community (EC) Number: 233-920-8
• UNII: 413S8C56GB
• DSSTox Substance ID: DTXSID2051475
• Nikkaji Number: J35.355H
• Wikidata: Q27258384
• Mol file: 10436-39-2.mol

Synonyms:1,1,2,3-tetrachloro-2-propene;1,1,2,3-tetrachloropropene;1,1,2,3-tetrachloropropylene;tetrachloropropene;tetrachloropropylene

Chemical Property of 1,1,2,3-Tetrachloropropene

Chemical Property:

• Appearance/Colour: clear colorless to yellowish liquid after melting
• Vapor Pressure: 1.66mmHg at 25°C
• Melting Point: 29-31°C(lit.)
• Refractive Index: 1.5121 (estimate)
• Boiling Point: 173.8°Cat760mmHg
• Flash Point: 62.3°C
• PSA: 0.00000
• Density: 1.539g/cm³
• LogP: 3.11070
• Storage Temp.: Refrigerator
• Solubility.: Chloroform, Methanol (Slightly)
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 179.888111
• Heavy Atom Count: 7
• Complexity: 80.9

Purity/Quality:

98% ^*data from raw suppliers

1,1,2,3-Tetrachloropropene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,C
• Hazard Codes: Xi,C

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Halogenated Aliphatics, Unsaturated
• Canonical SMILES: C(C(=C(Cl)Cl)Cl)Cl
• Uses: 1,1,2,3-Tetrachloropropene is used in producing 2,3,3,3-Tetrachloropropene. 2,3,3,3-Tetrachloropropene may be useful as heat transfer compns., aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymn.

Technology Process of 1,1,2,3-Tetrachloropropene

There total 22 articles about 1,1,2,3-Tetrachloropropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1,1,2,2,3-pentachloropropane (16714-68-4) → 1,1,2,3-Tetrachloropropene (10436-39-2)

Guidance literature:

With sodium hydroxide; cetylpyridinium bromide; at 130 ℃; for 2h;

DOI:10.1055/s-1982-29852

Reference yield: 90.0%

1,1,1,2,2,3-hexachloropropane (24425-97-6) → 1,1,2,3-Tetrachloropropene (10436-39-2)

Guidance literature:

With hydrogenchloride; zinc; In 1,4-dioxane; water; at 45 ℃; for 49h; Autoclave; Inert atmosphere;

Reference yield: 82.9%

1,1,1,3-tetrachloropropane (1070-78-6) → 1,1,1,2,3-pentachloro-propane (21700-31-2) + 3,3-dichloroallyl chloride (2567-14-8) + 1,1,2,3-Tetrachloropropene (10436-39-2)

Guidance literature:

With iron(III) chloride; chlorine; at 82 ℃; for 15.33h; under 1277.21 Torr; Product distribution / selectivity;

upstream raw materials:

1,1,1,2,3-pentachloro-propane

1,1,2,2,3-pentachloropropane

2,3,3,3-tetrachloropropene

methanol

Downstream raw materials:

Phenyl-<2,3,3-trichlor-allylether>

phenyl-(2,3,3-trichloro-allyl)-sulfide

1,1,2-Trichlor-3-(2,4,6-trimethyl-phenyl)-propen

1,1,2-trichloro-3-phenyl-propene

Refernces

• 1、 Chin-Hsien, Wang. "Elimination Reactions of Polyhalopropanes under Emulsion Catalytic Conditions to give Halopropenes". . p. 494 - 496. Retrieved 1982.
• 2、 -. "GALLIUM CATALYZED DEHYDROCHLORINATION OF A CHLORINATED ALKANE". Paragraph 0066. . Retrieved 2020/03/15.
• 3、 -. "METHOD FOR PRODUCING 2-CHLORO-3,3,3-TRIFLUOROPROPENE". Paragraph 0027. . Retrieved 2019/02/13.