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CAS No.: | 10436-39-2 |
---|---|
Name: | Tetrachloropropene |
Article Data: | 33 |
Molecular Structure: | |
Formula: | C3H2 Cl4 |
Molecular Weight: | 179.861 |
Synonyms: | Propene,1,1,2,3-tetrachloro- (6CI,7CI,8CI); 1,1,2,3-Tetrachloro-1-propene;1,1,2,3-Tetrachloropropene; 2,3,3-Trichloroallyl chloride; HCO 1230; HCO 1230xa |
Density: | 1.539g/cm3 |
Melting Point: | 29-31°C(lit.) |
Boiling Point: | 173.8°Cat760mmHg |
Flash Point: | 62.3°C |
Solubility: | MISCIBLE |
Appearance: | clear colorless to yellowish liquid after melting |
Hazard Symbols: | Xi,C |
Risk Codes: | R37/38; R41; R36/37/38; R34 |
Safety: | Poison by ingestion and skin contact. Moderately toxic by inhalation. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC. |
PSA: | 0.00000 |
LogP: | 3.11070 |
1,1,2,2,3-pentachloropropane
1,1,2,3-Tetrachloropropene
Conditions | Yield |
---|---|
With sodium hydroxide; cetylpyridinium bromide at 130℃; for 2h; | 97% |
With potassium hydroxide | |
With sodium hydroxide |
1,1,1,2,2,3-hexachloropropane
1,1,2,3-Tetrachloropropene
Conditions | Yield |
---|---|
With hydrogenchloride; zinc In 1,4-dioxane; water at 45℃; for 49h; Autoclave; Inert atmosphere; | 90% |
1,1,1,3-tetrachloropropane
A
1,1,1,2,3-pentachloro-propane
B
3,3-dichloroallyl chloride
C
1,1,2,3-Tetrachloropropene
Conditions | Yield |
---|---|
With iron(III) chloride; chlorine at 82℃; under 1277.21 Torr; for 15.33h; Product distribution / selectivity; | A 82.9% B 3.4% C 8.1% |
1,1,1,2,3-pentachloro-propane
A
1,1,2,3-Tetrachloropropene
B
2,3,3,3-tetrachloropropene
Conditions | Yield |
---|---|
With potassium hydroxide at 0℃; | |
With potassium hydroxide; Aliquat 336 In water at 80℃; for 3h; | |
With potassium hydroxide; Aliquat 336 In water at 80℃; for 3h; | |
With potassium hydroxide; Aliquat 336 In water at 8℃; for 3h; |
2,3,3,3-tetrachloropropene
1,1,2,3-Tetrachloropropene
Conditions | Yield |
---|---|
at 180℃; | |
With aluminium trichloride at 0℃; | |
With antimonypentachloride | |
at 150 - 180℃; |
methanol
2,3,3-trichloro-2-propen-1-ol
A
methyl 2-chloroacrylate
B
1,1,2,3-Tetrachloropropene
Conditions | Yield |
---|---|
With sulfuric acid; water 1) 105 deg C, 4 h, 2) 30 min; Yield given. Multistep reaction. Yields of byproduct given; |
1,1,1,2,3-pentachloro-propane
A
3,3,3-trichloro-1-propene
B
1,1,2,3-Tetrachloropropene
Conditions | Yield |
---|---|
at 400℃; under 750.075 Torr; for 0.0130556h; Inert atmosphere; |
1,1,1,2,3-pentachloro-propane
A
2,3-dichloro-3,3-difluoroprop-1-ene
B
1,1,2,3-Tetrachloropropene
C
1,1,2,3-tetrachloro-1-fluoro-propane
Conditions | Yield |
---|---|
With hydrogen fluoride at 290℃; under 750.075 Torr; for 3h; Inert atmosphere; tubular reactor; |
Conditions | Yield |
---|---|
Stage #1: prop-1-yne With chlorine at 60 - 80℃; Stage #2: With chlorine; dibenzoyl peroxide at 40 - 50℃; Stage #3: With sodium hydroxide at 40 - 50℃; |
Conditions | Yield |
---|---|
at 100 - 450℃; under 1018.63 Torr; Temperature; Reagent/catalyst; Pressure; Inert atmosphere; | 8.1 %Spectr. |
IUPAC Name: 1,1,2,3-Tetrachloroprop-1-ene
The MF of 1,1,2,3-Tetrachloropropene (CAS NO.10436-39-2) is C3H2Cl4.
The MW of 1,1,2,3-Tetrachloropropene (CAS NO.10436-39-2) is 179.86.
Synonyms of 1,1,2,3-Tetrachloropropene (CAS NO.10436-39-2): Tetrachloropropene ; 1,1,2,3-Tetrachloropropene ; 1,1,2,3-Tetrachloro-1-propene ; 1,1,2,3-Tetrachloro-propen ; 2,3,3-Trichloroallyl chloride
Apperance: Colorless oily liquid
Index of Refraction: 1.512
EINECS: 233-920-8
Density: 1.539 g/ml
Flash Point: 62.3 °C
Boiling Point: 173.8 °C
1,1,2,3-Tetrachloropropene (CAS NO.10436-39-2) is Ye Yan fear herbicide intermediate and used for the synthesis of heat-resistant plastic.
A dehydrochlorination: tirring 1,1,2,3 - Tetrachloro-propane,calcium hydroxide and a certain amount of water in the reactors, to a certain reaction temperature for several hours, add 1:1 hydrochloric acid and in to acidic deposition layered collection of mixed-bit three allyl chloride.
Secondary chloride: reaction equipment is the same chlorination, mixed with bits into three allyl chloride, were mixed with bits 5-chloropropane.
Second dehydrochlorination: Production equipment is the same dehydrochlorination in the reaction vessel into position five chlorine mixed with propane, adding calcium hydroxide, dehydrochlorination was four allyl chloride.
ClCH=CHCH2Cl+Cl2→ClCH2CHClCHCl2
ClCH2CHClCHCl2+OH-→ClCH2ClG=CHCl
ClCH2ClC=CHCl+Cl2→Cl2CHCCl2CH2Cl
Cl2CHCCl2CH2Cl+OH-→Cl2C=CClCH2Cl
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LC50 | inhalation | 3200mg/m3 (3200mg/m3) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(10), Pg. 51, 1979. | |
mouse | LD50 | oral | 800mg/kg (800mg/kg) | LIVER: OTHER CHANGES | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 43(4), Pg. 15, 1978. |
rabbit | LD50 | oral | 477mg/kg (477mg/kg) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(10), Pg. 51, 1979. | |
rabbit | LD50 | skin | 400uL/kg (0.4mL/kg) | American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969. | |
rat | LC50 | inhalation | 1500mg/m3 (1500mg/m3) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(10), Pg. 51, 1979. | |
rat | LD50 | oral | 350mg/kg (350mg/kg) | American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969. |
Reported in EPA TSCA Inventory.
Poison by ingestion and skin contact. Moderately toxic by inhalation. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC.