Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂

Base Information

Chemical Name:Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂
CAS No.:213205-67-5
Molecular Formula:C₄₂H₃₃Bi₃
Molecular Weight:1164.67
Hs Code.:

Ph<sub>2</sub>Bi-C<sub>6</sub>H<sub>4</sub>-Bi(Ph)-C<sub>6</sub>H<sub>4</sub>-BiPh<sub>2</sub>

Synonyms:Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂

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Chemical Property of Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂

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Technology Process of Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂

There total 3 articles about Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: Ph₂Cl₂Bi-C₆H₄-BiCl₂Ph-C₆H₄-BiCl₂Ph₂

: 213205-67-5
Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂

Guidance literature:: With Na₂S₂O₃; In dichloromethane; water; Ar-atmosphere; stirring for 8 h; sepn. of org. layer, extn. of aq. layer (CH2Cl2), evapn., chromy. (Al2O3), GPC;

Reference yield: 28.0%

: diphenylbismuth triflate-HMPA complex

: 106-37-6
1.4-dibromobenzene

: 213205-67-5
Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂

: 213205-68-6
Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂

: 603-33-8
triphenylbismuthane

: 15925-07-2
p-bis(diphenylbismuthino)benzene

Guidance literature:: With MgCl₂, K, KI; In tetrahydrofuran; Ar-atmosphere; refluxing MgCl2, K (2 equivs.) and KI for 3 h (pptn. of metal magnesium), addn. of Br2C6H4, stirring for 3 h at room temp., addn.of Bi-complex, stirring for 3 h at room temp.; addn. of brine, sepn. of org. layer, extn. of aq. layer (EtOAc), drying (MgSO4), evapn., filtration (Al2O3, hexanes:EtOAc), GPC, recrystn. (MeOH);

Reference yield: 27.0%

: 106-37-6
1.4-dibromobenzene

: 7787-60-2
bismuth(III) chloride

: 603-33-8
triphenylbismuthane

: 213205-67-5
Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂

: 213205-68-6
Ph₂Bi-C₆H₄-Bi(Ph)-C₆H₄-Bi(Ph)-C₆H₄-BiPh₂

: 15925-07-2
p-bis(diphenylbismuthino)benzene

Guidance literature:: With t-BuLi; CuBr*SMe₂; In tetrahydrofuran; pentane; Ar-atmosphere; addn. of t-BuLi (4.4 equivs., pentane) to soln. of Br2C6H4 (THF), addn. of CuBr*SMe2 at -78°C, stirring for 20 min, addn. of Ph2BiCl (in situ prepared from Ph3Bi and BiCl3, THF), stirring (1 h at 0°C); addn. of brine, sepn. of org. layer, extn. of aq. layer (EtOAc), drying (MgSO4), evapn., filtration (SiO2, hexane:EtOAc), GPC, recrystn. (MeOH);