C₉H₁₃BO₃

Base Information

• Chemical Name: C₉H₁₃BO₃
• CAS No.: 157670-38-7
• Molecular Formula: C₉H₁₃BO₃
• Molecular Weight: 180.011
• Mol file: 157670-38-7.mol

Synonyms:C₉H₁₃BO₃

Chemical Property of C₉H₁₃BO₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₉H₁₃BO₃

There total 5 articles about C₉H₁₃BO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + 3-methoxyphenyl-N,N-diisopropylaminoborane → C9H13BO3 (157670-38-7)

Guidance literature:

at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.tetlet.2014.01.080

Reference yield:

3-methoxyphenyl bromide (2398-37-0) → C9H13BO3 (157670-38-7)

Guidance literature:

3-methoxyphenyl bromide; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2h; Inert atmosphere;

With Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/jo100611k

Reference yield:

3-methoxyphenyl bromide (2398-37-0) + Trimethyl borate (121-43-7,63156-11-6) → C9H13BO3 (157670-38-7)

Guidance literature:

3-methoxyphenyl bromide; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere; Schlenk technique;

Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1021/ja311689k

upstream raw materials:

3-methoxyphenyl bromide

Trimethyl borate

methanol

m-Anisidine

Downstream raw materials:

(E)-2-(3-methoxy-2-(2-methylstyryl)phenyl)pyridine

(E)-2-(5-methoxy-2-(2-methylstyryl)phenyl)pyridine

2-(3-methoxyphenyl)pyridine

3-methoxyphenylboronic acid

Refernces

• 1、 Guerrand, Hélène D. S.,Vaultier, Michel,Pinet, Sandra,Pucheault, Mathieu. "Amine-borane complexes: Air- and moisture-stable partners for palladium-catalyzed borylation of aryl bromides and chlorides". . p. 1167 - 1174. Retrieved 2015/04/22.
• 2、 Marciasini, Ludovic D.,Vaultier, Michel,Pucheault, Mathieu. "Borylation using group IV metallocene under mild conditions". supporting information. p. 1702 - 1705. Retrieved 2014/03/21.