p-(acetyl-N-methyl)aminophenyl azide

Base Information

• Chemical Name: p-(acetyl-N-methyl)aminophenyl azide
• CAS No.: 178100-44-2
• Molecular Formula: C₉H₁₀N₄O
• Molecular Weight: 190.205
• Mol file: 178100-44-2.mol

Synonyms:p-(acetyl-N-methyl)aminophenyl azide

Chemical Property of p-(acetyl-N-methyl)aminophenyl azide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-(acetyl-N-methyl)aminophenyl azide

There total 5 articles about p-(acetyl-N-methyl)aminophenyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4-(N-methylacetamido)aniline (119-63-1) → p-(acetyl-N-methyl)aminophenyl azide (178100-44-2)

Guidance literature:

4-(N-methylacetamido)aniline; With hydrogenchloride; sodium nitrite; at 0 - 5 ℃; for 1h;

With sodium azide; In water; at 0 - 20 ℃; for 1h;

DOI:10.1246/bcsj.71.1259

Reference yield:

p-(acetylamino)phenyl azide (52578-66-2) + methyl iodide (74-88-4) → p-(acetyl-N-methyl)aminophenyl azide (178100-44-2)

Guidance literature:

With sodium hydride; In dimethyl sulfoxide; at 20 ℃; for 1h;

DOI:10.1139/v01-178

Reference yield:

N-methyl-N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)acetamide (1056456-21-3) → p-(acetyl-N-methyl)aminophenyl azide (178100-44-2)

Guidance literature:

With sodium azide; copper diacetate; In methanol; at 55 ℃; for 24h;

DOI:10.1021/jacs.8b00503

upstream raw materials:

4-(N-methylacetamido)aniline

p-(acetylamino)phenyl azide

methyl iodide

N-acetyl-p-phenylenediamine

Downstream raw materials:

quinoneimine

p-benzoquinone