2,4,6-tri-tert-butylphenylphosphinic acid

Base Information

• Chemical Name: 2,4,6-tri-tert-butylphenylphosphinic acid
• CAS No.: 107394-70-7
• Molecular Formula: C₁₈H₃₁O₂P
• Molecular Weight: 310.417
• Mol file: 107394-70-7.mol

Synonyms:2,4,6-tri-tert-butylphenylphosphinic acid

Chemical Property of 2,4,6-tri-tert-butylphenylphosphinic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4,6-tri-tert-butylphenylphosphinic acid

There total 27 articles about 2,4,6-tri-tert-butylphenylphosphinic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C22H39O3P2(1-) + benzaldehyde (100-52-7) → (E)-1,2-diphenyl-ethene (103-30-0) + 2,4,6-tri-tert-butylphenylphosphinic acid (107394-70-7)

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; In tetrahydrofuran; water; at 20 ℃;

Reference yield:

triphenyl phosphite ozonide (29833-83-8) + Bis(2,4,6-tri-tert-butylphenyl)diphosphen (83466-54-0,93602-74-5,79073-99-7) → phosphoric acid triphenyl ester (115-86-6) + 2,4,6-tri-tert-butylphenylphosphinic acid (107394-70-7) + 2,4,6-tri-t-butylphenylphosphonic acid

Guidance literature:

Multistep reaction; 1) 80 deg C; 2) RT;

Reference yield:

1-(2,4,6-tri-t-butylphenyl)-2-phenyl-1-phosphaethene (143372-18-3,99364-93-9,99364-92-8) + benzaldehyde (100-52-7) → (E)-1,2-diphenyl-ethene (103-30-0) + 2,4,6-tri-tert-butylphenylphosphinic acid (107394-70-7)

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; In water; stereoselective reaction;

DOI:10.1021/jacs.7b00428

upstream raw materials:

triphenyl phosphite ozonide

Bis(2,4,6-tri-tert-butylphenyl)diphosphen

o-Phenylen-phenyl-phosphit-ozonid

C₁₅H₂₇O₉P