octa-2,7-dienyloxybenzene

Base Information

• Chemical Name: octa-2,7-dienyloxybenzene
• CAS No.: 13846-40-7
• Molecular Formula: C₁₄H₁₈O
• Molecular Weight: 202.296
• Mol file: 13846-40-7.mol

Synonyms:octa-2,7-dienyloxybenzene

Chemical Property of octa-2,7-dienyloxybenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of octa-2,7-dienyloxybenzene

There total 4 articles about octa-2,7-dienyloxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) + phenol (108-95-2,27073-41-2) → octa-2,7-dienyloxybenzene (13846-40-7)

Guidance literature:

With sodium phenoxide; [IMesPd⁽⁰⁾dvds]; at 70 ℃; for 16h;

DOI:10.1002/chem.200400182

Reference yield:

buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) + phenol (108-95-2,27073-41-2) → 3-Phenoxy-1,7-octadien (15972-91-5) + octa-2,7-dienyloxybenzene (13846-40-7)

Guidance literature:

With sodium phenoxide; [(1,3-dimesitylimidazol-2-ylidene)Pd(O(SiMe₂CH=CH₂)2)]; In tetrahydrofuran; at 90 ℃; for 16h;

DOI:10.1002/1521-3773(20020315)41:6<986::AID-ANIE986>3.0.CO;2-M

Reference yield:

buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) + phenol (108-95-2,27073-41-2) → 3-Phenoxy-1,7-octadien (15972-91-5) + 3-methylallyloxy benzene (14503-58-3) + (but-3-en-2-yloxy)benzene (22509-78-0) + octa-2,7-dienyloxybenzene (13846-40-7)

Guidance literature:

With bis(acetylacetonato)palladium(II); at 80 ℃; for 1h; Schlenk technique; Inert atmosphere; High pressure;

DOI:10.1039/c3cy00188a

upstream raw materials:

buta-1,3-diene

phenol

Downstream raw materials:

8-Phenoxy-6-octen-1-ol

1-Benzyloxy-2,7-octadien

3-Benzyloxy-1,7-octadien

N-methyl-N'-(2,7-octadienyl)-p-toluenesulfamide