methyl 2-{1-[(benzyloxy)amino]-3-methoxy-1,3-dioxopropan-2-yl}-5-nitrobenzoate

Base Information

Chemical Name:methyl 2-{1-[(benzyloxy)amino]-3-methoxy-1,3-dioxopropan-2-yl}-5-nitrobenzoate
CAS No.:1383786-17-1
Molecular Formula:C₁₉H₁₈N₂O₈
Molecular Weight:402.361
Hs Code.:

Synonyms:methyl 2-{1-[(benzyloxy)amino]-3-methoxy-1,3-dioxopropan-2-yl}-5-nitrobenzoate

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Chemical Property of methyl 2-{1-[(benzyloxy)amino]-3-methoxy-1,3-dioxopropan-2-yl}-5-nitrobenzoate

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Technology Process of methyl 2-{1-[(benzyloxy)amino]-3-methoxy-1,3-dioxopropan-2-yl}-5-nitrobenzoate

There total 3 articles about methyl 2-{1-[(benzyloxy)amino]-3-methoxy-1,3-dioxopropan-2-yl}-5-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 622-33-3
N-benzyloxyamine

: 1026038-35-6
methyl 2-(1,3-dimethoxy-1,3-dioxopropan-2-yl)-5-nitrobenzoate

: 1383786-17-1
methyl 2-{1-[(benzyloxy)amino]-3-methoxy-1,3-dioxopropan-2-yl}-5-nitrobenzoate

Guidance literature:: N-benzyloxyamine; methyl 2-(1,3-dimethoxy-1,3-dioxopropan-2-yl)-5-nitrobenzoate; In toluene; for 8h; Reflux;

for 12h;

Reference yield:

: 2965-22-2
methyl 2-fluoro-5-nitro-benzoate

: 1383786-17-1
methyl 2-{1-[(benzyloxy)amino]-3-methoxy-1,3-dioxopropan-2-yl}-5-nitrobenzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / 20 °C / Inert atmosphere

1.2: 15 h / Inert atmosphere; Reflux

2.1: toluene / 15 h / Reflux; Dean-Stark

With sodium hydride; In tetrahydrofuran; toluene; mineral oil;
DOI:10.1021/jm500109z

Reference yield:

: 7304-32-7
2-fluoro-5-nitrobenzoic acid

: 1383786-17-1
methyl 2-{1-[(benzyloxy)amino]-3-methoxy-1,3-dioxopropan-2-yl}-5-nitrobenzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: thionyl chloride / 24 h / 0 °C / Reflux

2.1: sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / 20 °C / Inert atmosphere

2.2: 15 h / Inert atmosphere; Reflux

3.1: toluene / 15 h / Reflux; Dean-Stark

With thionyl chloride; sodium hydride; In tetrahydrofuran; toluene; mineral oil;
DOI:10.1021/jm500109z