9,10-Dihydro-9,10-[1,2]benzenoanthracene-9-yl bromide

Base Information

• Chemical Name: 9,10-Dihydro-9,10-[1,2]benzenoanthracene-9-yl bromide
• CAS No.: 15364-55-3
• Molecular Formula: C20H13 Br
• Molecular Weight: 333.227
• Hs Code.: 2902900000
• Mol file: 15364-55-3.mol

Synonyms:9,10-o-Benzenoanthracene,9-bromo-9,10-dihydro- (6CI,7CI,8CI); 1-Bromotribenzobicyclo[2.2.2]octatriene;9-Bromotriptycene; 9-Bromotryptycene; 9-Triptycenyl bromide

Chemical Property of 9,10-Dihydro-9,10-[1,2]benzenoanthracene-9-yl bromide

Chemical Property:

• Vapor Pressure: 7.66E-06mmHg at 25°C
• Melting Point: 252.0 to 256.0 °C
• Boiling Point: 386.8°C at 760 mmHg
• Flash Point: 171.7°C
• PSA: 0.00000
• Density: 1.504g/cm³
• LogP: 5.18040

Purity/Quality:

97% ^*data from raw suppliers

9-Bromo-9,10-dihydro-9,10-[1,2]benzenoanthracene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 9-Bromo-9,10-dihydro-9,10-[1,2]benzenoanthracene can be used as reactant/reagent in reaction with selenium to obtain triselenide.

Technology Process of 9,10-Dihydro-9,10-[1,2]benzenoanthracene-9-yl bromide

There total 11 articles about 9,10-Dihydro-9,10-[1,2]benzenoanthracene-9-yl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

9-Bromoanthracene (1564-64-3) + anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → 9-bromotriptycene (15364-55-3)

Guidance literature:

With isopentyl nitrite; In 1,2-dimethoxyethane; dichloromethane; for 1h; Heating;

DOI:10.1021/ja00344a006

Reference yield:

(trimethylstannyl)lithium (17946-71-3) + 9-bromo-10-iodotriptycene (347360-84-3) → triptycene (477-75-8) + 9-bromotriptycene (15364-55-3) + C20H12Sn(CH3)3Br + C20H12ISn(CH3)3

Guidance literature:

In tetrahydrofuran; at 0 ℃; Further Variations:; Reagents; Product distribution;

DOI:10.1021/jo001638w

Reference yield:

9-bromo-9,10-dihydro-9,10-o-benzeno-anthracene-1,4-diyldiamine → 9-bromotriptycene (15364-55-3)

Guidance literature:

With hypophosphorous acid; acetic acid; sodium nitrite;

DOI:10.1021/ja01158a093

upstream raw materials:

9-Brom-12,15-dihydroxy-11,12,15,16-tetrahydro-triptycen

9-Bromoanthracene

anthranilic acid

9,10-dibromotriptycene

Downstream raw materials:

(triptycyl-1)diphenyl carbinol

9-Benzolazo-triptycen

triptycene

9-Triptycyldiphenylphosphine oxide