(2R,3S)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

Base Information

Chemical Name:(2R,3S)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid
CAS No.:307503-09-9
Molecular Formula:C₉H₁₀O₅
Molecular Weight:198.175
Hs Code.:

Synonyms:(2R,3S)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

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Chemical Property of (2R,3S)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

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Technology Process of (2R,3S)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

There total 4 articles about (2R,3S)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 6118-51-0
exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

: 67-56-1
methanol

: 307503-09-9
(2R,3S)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

Guidance literature:: With C₂₈H₂₇F₆N₃O₃S; In tetrahydrofuran; at 25 ℃; for 24h; enantioselective reaction; Inert atmosphere;
DOI:10.1039/c9cc03895g

Reference yield:

: 6118-51-0
exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

: 67-56-1
methanol

: 307503-09-9
(2R,3S)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

: 104485-82-7
(2S,3R)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

Guidance literature:: With quinidine; In tetrachloromethane; toluene; at -55 ℃; for 60h; Title compound not separated from byproducts.;
DOI:10.1021/jo000638t

Reference yield:

: 6118-51-0
exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

: 67-56-1
methanol

: 7-oxa-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid monomethyl ester

: 307503-09-9
(2R,3S)-3-exo-methoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-ene-2-exo-carboxylic acid

Guidance literature:: 1-[3,5-(CF₃)2-phenyl]-3-(quinin-9-yl)thiourea; In various solvent(s); at 20 ℃; for 130h; Title compound not separated from byproducts.;
DOI:10.1021/jo702639h