methyl 2-methylphenyl carbonate

Base Information

• Chemical Name: methyl 2-methylphenyl carbonate
• CAS No.: 1848-03-9
• Molecular Formula: C₉H₁₀O₃
• Molecular Weight: 166.177
• Mol file: 1848-03-9.mol

Synonyms:methyl 2-methylphenyl carbonate

Chemical Property of methyl 2-methylphenyl carbonate

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2-methylphenyl carbonate

There total 4 articles about methyl 2-methylphenyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

ortho-cresol (95-48-7,77504-84-8) + methyl chloroformate (79-22-1) → methyl 2-methylphenyl carbonate (1848-03-9)

Guidance literature:

With triethylamine; In dichloromethane; at 5 - 20 ℃;

DOI:10.1021/jo000532y

Reference yield: 75.0%

methanol (67-56-1) + carbon dioxide (124-38-9,18923-20-1) + ortho-cresol (95-48-7,77504-84-8) → methyl 2-methylphenyl carbonate (1848-03-9)

Guidance literature:

With N,N,N',N'-tetramethylguanidine; In dimethyl sulfoxide; at 20 ℃; under 760.051 Torr; Irradiation; Sealed tube;

DOI:10.1039/d1cc05833a

Reference yield: 4.2%

ortho-cresol (95-48-7,77504-84-8) + carbonic acid dimethyl ester (616-38-6) → di-o-tolyl carbonate (617-09-4) + methyl 2-methylphenyl carbonate (1848-03-9)

Guidance literature:

With 1-methyl-2-oxopyrrolidinium hydrogen sulfate; di(n-butyl)tin oxide; at 180 - 200 ℃; for 12h; Inert atmosphere;

DOI:10.1016/j.catcom.2010.09.017

upstream raw materials:

ortho-cresol

methyl chloroformate

carbonic acid dimethyl ester

methanol

Downstream raw materials:

2-methylmethoxybenzene