Cr(CO)4((P,P)-κ2-((o-MeOC6H4)2PN(CH3)P(o-Me3OC6H4)2))*CH2Cl2

Base Information

• Chemical Name: Cr(CO)4((P,P)-κ2-((o-MeOC6H4)2PN(CH3)P(o-Me3OC6H4)2))*CH2Cl2
• CAS No.: 934754-27-5
• Molecular Formula: CH₂Cl₂*C₃₃H₃₁CrNO₈P₂
• Molecular Weight: 768.487
• Mol file: 934754-27-5.mol

Synonyms:Cr(CO)4((P,P)-κ2-((o-MeOC6H4)2PN(CH3)P(o-Me3OC6H4)2))*CH2Cl2

Chemical Property of Cr(CO)4((P,P)-κ2-((o-MeOC6H4)2PN(CH3)P(o-Me3OC6H4)2))*CH2Cl2

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of Cr(CO)4((P,P)-κ2-((o-MeOC6H4)2PN(CH3)P(o-Me3OC6H4)2))*CH2Cl2

There total 1 articles about Cr(CO)4((P,P)-κ2-((o-MeOC6H4)2PN(CH3)P(o-Me3OC6H4)2))*CH2Cl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

dichloromethane (75-09-2) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6) + N-[bis(2-methoxyphenyl)phosphino]-P,P-bis(2-methoxyphenyl)-N-methylphosphinous amide (197798-18-8) → Cr(CO)4((P,P)-κ2-((o-MeOC6H4)2PN(CH3)P(o-Me3OC6H4)2))*CH2Cl2 (934754-27-5)

Guidance literature:

In toluene; (N2); using Schlenk techniques; stirring of toluene soln. of Cr(CO)6 andMeN(P(C6H4OCH3)2)2 at 110°C for 36 h in sealed tube; removal of volatiles in vac., dissolving in CH2Cl2, filtration, cooling to -35°C; decanting of mother liquor; drying in vac., elem. anal.;

DOI:10.1021/om050605+

upstream raw materials:

dichloromethane

chromium⁽⁰⁾ hexacarbonyl

N-[bis(2-methoxyphenyl)phosphino]-P,P-bis(2-methoxyphenyl)-N-methylphosphinous amide