Benzoic acid (R)-7-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methylene-heptyl ester

Base Information

Chemical Name:Benzoic acid (R)-7-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methylene-heptyl ester
CAS No.:208658-97-3
Molecular Formula:C₂₈H₄₀O₄Si
Molecular Weight:468.709
Hs Code.:

Synonyms:Benzoic acid (R)-7-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methylene-heptyl ester

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Chemical Property of Benzoic acid (R)-7-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methylene-heptyl ester

Chemical Property:

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Technology Process of Benzoic acid (R)-7-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methylene-heptyl ester

There total 7 articles about Benzoic acid (R)-7-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methylene-heptyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 208658-95-1
Benzoic acid (R)-7-benzyloxy-3-hydroxy-5-methylene-heptyl ester

: 208658-97-3
Benzoic acid (R)-7-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methylene-heptyl ester

Guidance literature:: DOI:10.1016/S0040-4039(98)00682-0

Reference yield:

: 58558-53-5
(((3-methylbut-3-en-1-yl)oxy)methyl)benzene

: 208658-97-3
Benzoic acid (R)-7-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methylene-heptyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 49 percent / EtAlCl₂

2: 94 percent / DIBAL-H

3: 88 percent / D-(+)-DET, Ti(O-i-Pr)4, t-BuOOH

4: 93 percent / Red-Al

5: 93 percent

6: 97 percent

With titanium(IV) isopropylate; tert.-butylhydroperoxide; D-(+)-DET; ethylaluminum dichloride; diisobutylaluminium hydride; sodium bis(2-methoxyethoxy)aluminium dihydride;
DOI:10.1016/S0040-4039(98)00682-0

Reference yield:

: (E)-7-Benzyloxy-5-methylene-hept-2-enoic acid ethyl ester

: 208658-97-3
Benzoic acid (R)-7-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methylene-heptyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 94 percent / DIBAL-H

2: 88 percent / D-(+)-DET, Ti(O-i-Pr)4, t-BuOOH

3: 93 percent / Red-Al

4: 93 percent

5: 97 percent

With titanium(IV) isopropylate; tert.-butylhydroperoxide; D-(+)-DET; diisobutylaluminium hydride; sodium bis(2-methoxyethoxy)aluminium dihydride;
DOI:10.1016/S0040-4039(98)00682-0