4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester

Base Information

Chemical Name:4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester
CAS No.:866363-67-9
Molecular Formula:C₁₈H₁₇Cl₂O₄PS
Molecular Weight:431.276
Hs Code.:

Synonyms:4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester

Suppliers and Price of 4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester

There total 3 articles about 4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 866363-66-8
thioacetic acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester

: 108-55-4
glutaric anhydride,

: 866363-67-9
4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester

Guidance literature:: thioacetic acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester; With sodium methylate; In N,N-dimethyl-formamide; at 0 ℃; for 2h;

glutaric anhydride,; In N,N-dimethyl-formamide; at 0 ℃; for 0.333333h;
DOI:10.1021/jo0505472

Reference yield:

: 13685-36-4
Bis-(p-chlorphenyl)-chlormethylphosphinoxid

: 866363-67-9
4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 2.1 g / tetrahydrofuran / Heating

2.1: NaOMe / dimethylformamide / 2 h / 0 °C

2.2: 53 percent / dimethylformamide / 0.33 h / 0 °C

With sodium methylate; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jo0505472

Reference yield:

: 873-77-8
(4-chlorphenyl)magnesium bromide

: 866363-67-9
4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: tetrahydrofuran; diethyl ether / 24 h / Heating

2.1: 2.1 g / tetrahydrofuran / Heating

3.1: NaOMe / dimethylformamide / 2 h / 0 °C

3.2: 53 percent / dimethylformamide / 0.33 h / 0 °C

With sodium methylate; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo0505472