bis(1,10-phenanthroline)copper(1+) ion

Base Information

• Chemical Name: bis(1,10-phenanthroline)copper(1+) ion
• CAS No.: 17378-82-4
• Molecular Formula: C24H16 Cu N4
• Molecular Weight: 423.964
• Mol file: 17378-82-4.mol

Synonyms:Copper(1+),bis(1,10-phenanthroline)-, ion (8CI); Copper(1+),bis(1,10-phenanthroline-N1,N10)-, (T-4)-; Bis(1,10-phenanthroline)copper(1+);Di(1,10-phenanthroline)copper(1+)

Chemical Property of bis(1,10-phenanthroline)copper(1+) ion

Chemical Property:

• Vapor Pressure: 3.38E-05mmHg at 25°C
• Boiling Point: 365.1°Cat760mmHg
• Flash Point: 164.8°C
• PSA: 51.56000
• Density: g/cm³
• LogP: 5.56350

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(1,10-phenanthroline)copper(1+) ion

There total 6 articles about bis(1,10-phenanthroline)copper(1+) ion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,10-Phenanthroline (66-71-7) + copper(ll) bromide (7789-45-9) → bis(1,10-phenanthroline)copper(I) (17378-82-4) + bis(1,10-phenanthroline)copper(2+) (15823-71-9,889449-72-3)

Guidance literature:

With C₆H₅CH₂OH; Cs₂CO₃; In dimethylformamide-d7; room temp.; detected by NMR spectra;

DOI:10.1039/c0dt00632g

Reference yield:

copper(l) iodide (7681-65-4) + 1,10-Phenanthroline (66-71-7) + para-bromotoluene (106-38-7) + 2,4-Xylenol (105-67-9) → bis(1,10-phenanthroline)copper(I) (17378-82-4) + [Cu(I)(2,4-dimethylphenoxy)2](1-) + [Cu(I)(1,10-phenanthroline)(2,4-dimethylphenoxy)] + [Cu(I)(1,10-phenanthroline)(1-(2,4-dimethylphenoxy)-4-methylbenzene)](1+)

Guidance literature:

With potassium carbonate; In toluene; at 120 ℃; for 2h; Glovebox; Inert atmosphere;

DOI:10.1039/c4dt00582a

Reference yield:

1,10-Phenanthroline (66-71-7) + malachite + N-(N'-benzoyl-2-aminoethanoyl)-2-aminoethanoic acid (1145-32-0) + water (7732-18-5) → bis(1,10-phenanthroline)copper(I) (17378-82-4) + [Cu(benzoylglycilglycine)(1,10-phenanthroline)2](1+)*(benzoylglycilglycine)(1-)*6H2O

Guidance literature:

In water; basic copper carbonate and benzoylglycilglycine refluxed in water for 2 h, liq. filtered off and then solid phenanthroline added, few days; elem.anal.;

DOI:10.1016/j.ica.2009.06.042

upstream raw materials:

1,10-Phenanthroline

ortho-iodobenzoylglycilglycine

water

N-(N'-benzoyl-2-aminoethanoyl)-2-aminoethanoic acid

Downstream raw materials:

bis(1,10-phenanthroline)copper⁽²⁺⁾