1D-2,3,6-Tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol 1,4-bis(dibenzylphosphate)

Base Information

Chemical Name:1D-2,3,6-Tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol 1,4-bis(dibenzylphosphate)
CAS No.:145842-30-4
Molecular Formula:C₆₃H₆₄O₁₃P₂
Molecular Weight:1091.14
Hs Code.:

Synonyms:1D-2,3,6-Tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol 1,4-bis(dibenzylphosphate)

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Chemical Property of 1D-2,3,6-Tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol 1,4-bis(dibenzylphosphate)

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Technology Process of 1D-2,3,6-Tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol 1,4-bis(dibenzylphosphate)

There total 21 articles about 1D-2,3,6-Tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol 1,4-bis(dibenzylphosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: Phosphorous acid dibenzyl ester (1R,2R,3S,4R,5R,6R)-2,3,6-tris-benzyloxy-4-(bis-benzyloxy-phosphanyloxy)-5-(4-methoxy-benzyloxy)-cyclohexyl ester

: 145842-30-4
1D-2,3,6-Tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol 1,4-bis(dibenzylphosphate)

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid;
DOI:10.1016/0008-6215(92)85046-3

Reference yield:

: 112204-05-4,149057-08-9
(+/-)-3,6-di-O-allyl-1,2-O-cyclohexylidene-myo-inositol

: 138329-00-7,145842-30-4,149056-97-3
(+/-)-2,3,6-tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol 1,4-bis(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 7 steps

1: 53 percent / tetrabutylammonium hydrogen sulfate, 5percent aq. NaOH / CH₂Cl₂ / 24 h / Heating

2: NaH / dimethylformamide / 2 h / 20 °C

3: HCl / methanol / 5 h / 20 °C

4: 95 percent / NaH / dimethylformamide / 2 h / 20 °C

5: (1,5-cyclooctadiene)bis(methyldiphenylphosphine)iridium hexafluorophosphate / 1,2-dichloro-ethane / 4 h

6: 92 percent / HCl / CH₂Cl₂; methanol / 1 h / 20 °C

7: 1) 1H-tetrazole, 2) tert-butyl hydroperoxide / 1) CH₂Cl₂, acetonitrile, 15 min., 2) 0 deg C, 45 min.

With 1H-tetrazole; hydrogenchloride; tert.-butylhydroperoxide; sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; sodium hydride; (1,5-cyclooctadiene)bis(methyldiphenylphosphine)iridium hexafluorophosphate; In methanol; dichloromethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(92)85037-Z

Reference yield:

: 138328-97-9,149056-95-1
(+/-)-1,4-di-O-allyl-2,3,6-tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol

: 138329-00-7,145842-30-4,149056-97-3
(+/-)-2,3,6-tri-O-benzyl-5-O-p-methoxybenzyl-myo-inositol 1,4-bis(dibenzyl phosphate)

Guidance literature:: Multi-step reaction with 3 steps

1: (1,5-cyclooctadiene)bis(methyldiphenylphosphine)iridium hexafluorophosphate / 1,2-dichloro-ethane / 4 h

2: 92 percent / HCl / CH₂Cl₂; methanol / 1 h / 20 °C

3: 1) 1H-tetrazole, 2) tert-butyl hydroperoxide / 1) CH₂Cl₂, acetonitrile, 15 min., 2) 0 deg C, 45 min.

With 1H-tetrazole; hydrogenchloride; tert.-butylhydroperoxide; (1,5-cyclooctadiene)bis(methyldiphenylphosphine)iridium hexafluorophosphate; In methanol; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1016/0008-6215(92)85037-Z