6-O-ALPHA-D-GLUCOSYL-ALPHA-CYCLODEXTRIN MONO

Base Information

• Chemical Name: 6-O-ALPHA-D-GLUCOSYL-ALPHA-CYCLODEXTRIN MONO
• CAS No.: 10058-19-2
• Molecular Formula: C42H70 O35
• Molecular Weight: 1135
• Mol file: 10058-19-2.mol

Synonyms:Cyclomaltohexaose,6-O-a-D-glucopyranosyl- (7CI);2,4,7,9,12,14,17,19,22,24,27,29-Dodecaoxaheptacyclo[26.2.2.23,6.28,11.213,16.218,21.223,26]dotetracontane,a-cyclodextrin deriv.; 6-O-(a-Glucopyranosyl)-a-cyclodextrin; 6-O-a-D-Glucopyranosylcyclomaltohexaose;6-O-a-D-Glucosyl-a-cyclodextrin; Glucosyl-a-cyclodextrin; a-Glucosyl-a-cyclodextrin

Chemical Property of 6-O-ALPHA-D-GLUCOSYL-ALPHA-CYCLODEXTRIN MONO

Chemical Property:

• Boiling Point: 1519.6±65.0 °C(Predicted)
• PKA: 12.53±0.70(Predicted)
• PSA: 554.05000
• Density: 1.87±0.1 g/cm3(Predicted)
• LogP: -15.23060

Purity/Quality:

98%,99%, ^*data from raw suppliers

6-O-a-D-Glucosyl-a-cyclodextrin ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 6-O-ALPHA-D-GLUCOSYL-ALPHA-CYCLODEXTRIN MONO

There total 7 articles about 6-O-ALPHA-D-GLUCOSYL-ALPHA-CYCLODEXTRIN MONO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 61,64-di-O-(α-D-glucopyranosyl)-cyclomaltoheptaose (108202-93-3) + 6-O-α-D-Glucopyranosyl α-cyclodextrin (10058-19-2) + 6-O-α-D-glucopyranosyl-β-cyclodextrin (92517-02-7,127181-68-4,142187-75-5,149496-53-7) + alpha cyclodextrin (10016-20-3)

Guidance literature:

Multistep reaction. Further byproducts given; 1.) cyclomaltodextrin glucanotransferase enzyme, water, 55 deg C, 40 h, pH 7.6, 2.) 0.01 percent (w/v) glucoamylase GNL-2 enzyme, water, 40 deg C, 5 h;

DOI:10.1016/S0008-6215(00)90195-2

Reference yield:

maltosyl(α1->6)α-cyclodextrin (100817-30-9) → D-Glucose (2280-44-6) + 4-O-<4-O-(6-O-α-D-Glucopyranosyl-α-D-glucopyranosyl)-α-D-glucopyranosyl>-D-glucose (34336-93-1) + 63-O-α-Maltosylmaltotriose + 6-O-α-D-Glucopyranosyl α-cyclodextrin (10058-19-2)

Guidance literature:

With water; Taka-amylase A; at 40 ℃; for 80h; Further byproducts given;

Reference yield:

maltosyl(α1->6)α-cyclodextrin (100817-30-9) → 4-O-<4-O-(6-O-α-D-Glucopyranosyl-α-D-glucopyranosyl)-α-D-glucopyranosyl>-D-glucose (34336-93-1) + 63-O-α-Maltosylmaltotriose + 6-O-α-D-Glucopyranosyl α-cyclodextrin (10058-19-2) + 63-α-maltosylmaltotetrose

Guidance literature:

With water; Taka-amylase A; at 40 ℃; for 80h; Further byproducts given;

upstream raw materials:

maltosyl(α1->6)α-cyclodextrin

6-O-α-maltotriosyl-α-cyclodextrin

maltotriose

alpha cyclodextrin

Downstream raw materials:

C₄₂H₇₀O₃₅*C₆H₅NO₃

Refernces

• 1、 Hizukuri, Susumu,Abe, Jun-Ichi,Koizumi, Kyoko,Okada, Yasuyo,Kubota, Yoko,et al.. "HYDROLYSIS AND SYNTHESIS OF BRANCHED CYCLOMALTOHEXAOSES WITH Pseudomonas ISOAMYLASE". . p. 191 - 198. Retrieved 1989.
• 2、 Sakano, Yoshiyuki,Sano, Mutsumi,Kobayashi, Tsuneo. "Preparation and Enzymatic Hydrolysis of Maltosyl-α-cyclodextrin". . p. 3391 - 3398. Retrieved 2007/10/02.