1,3-Diiodoadamantane

Base Information

• Chemical Name: 1,3-Diiodoadamantane
• CAS No.: 23174-58-5
• Molecular Formula: C₁₀H₁₄I₂
• Molecular Weight: 388.03
• Mol file: 23174-58-5.mol

Synonyms:1,3-Diiodoadamantane

Chemical Property of 1,3-Diiodoadamantane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-Diiodoadamantane

There total 1 articles about 1,3-Diiodoadamantane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-dehydroadamantane (24569-89-9) → 1,3-dichloroadamantane (16104-50-0) + 1,3-Diiodoadamantane (23174-58-5) + 1-Chloro-3-iodoadamantane (60389-53-9) + 1-iodo-3-(3-chloroadamant-1-yl)-adamantane

Guidance literature:

With Iodine monochloride; In dichloromethane; at 0 ℃; Further Variations:; Reaction partners; Product distribution;

DOI:10.1021/ja000193q

Reference yield: 77.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1,3-Diiodoadamantane (23174-58-5) → 1,3-bis(2-hydroxymethyl)adamantane (17071-62-4)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tetrabutylammonium (cyano)trihydroborate; In acetonitrile; at 80 ℃; for 8h; Inert atmosphere;

DOI:10.1021/ja210585n

Reference yield:

1,3-Diiodoadamantane (23174-58-5) → adamantane (281-23-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 4 percent Chromat_. / Me₃SnLi / tetrahydrofuran / 0.5 h / Ambient temperature; other (trimethylstannyl)alkali reagent; also in the presence of tert-butylamine or dicyclohexylphosphine

2: Me₃SnLi / tetrahydrofuran / 0.5 h / Ambient temperature

With (trimethylstannyl)lithium; In tetrahydrofuran;

DOI:10.1021/jo00078a009

upstream raw materials:

1,3-dehydroadamantane

Downstream raw materials:

adamantane

1,3-dehydroadamantane

1-iodoadamantane

1,3-bis(2-hydroxymethyl)adamantane