1-Chloro-3-iodoadamantane

Base Information

• Chemical Name: 1-Chloro-3-iodoadamantane
• CAS No.: 60389-53-9
• Molecular Formula: C₁₀H₁₄ClI
• Molecular Weight: 296.579
• Mol file: 60389-53-9.mol

Synonyms:1-Chloro-3-iodoadamantane

Chemical Property of 1-Chloro-3-iodoadamantane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Chloro-3-iodoadamantane

There total 1 articles about 1-Chloro-3-iodoadamantane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-dehydroadamantane (24569-89-9) → 1,3-dichloroadamantane (16104-50-0) + 1,3-Diiodoadamantane (23174-58-5) + 1-Chloro-3-iodoadamantane (60389-53-9) + 1-iodo-3-(3-chloroadamant-1-yl)-adamantane

Guidance literature:

With Iodine monochloride; In dichloromethane; at 0 ℃; Further Variations:; Reaction partners; Product distribution;

DOI:10.1021/ja000193q

Reference yield:

1-Chloro-3-iodoadamantane (60389-53-9) → adamantane (281-23-2)

Guidance literature:

Multi-step reaction with 2 steps

1: Me₃SnLi / tetrahydrofuran / 0.5 h / Ambient temperature; other (trimethylstannyl)alkali reagent; also in the presence of tert-butylamine or dicyclohexylphosphine

2: Me₃SnLi / tetrahydrofuran / 0.5 h / Ambient temperature

With (trimethylstannyl)lithium; In tetrahydrofuran;

DOI:10.1021/jo00078a009

Reference yield:

1-Chloro-3-iodoadamantane (60389-53-9) → 1-chloroadamantane (935-56-8) + adamantane (281-23-2) + 1,3-dehydroadamantane (24569-89-9)

Guidance literature:

With trimethylstannylsodium; In tetrahydrofuran; for 0.5h; Ambient temperature;

DOI:10.1021/jo00078a009

upstream raw materials:

1,3-dehydroadamantane

Downstream raw materials:

1-chloroadamantane

adamantane

1,3-dehydroadamantane

1-iodoadamantane