methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate

Base Information

Chemical Name:methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate
CAS No.:1410840-49-1
Molecular Formula:C₂₅H₂₈O₄Si
Molecular Weight:420.58
Hs Code.:

Synonyms:methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate

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Technology Process of methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate

There total 1 articles about methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1410840-47-9
methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylate

: 1410840-49-1
methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate

Guidance literature:: methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylate; With tert.-butylhydroperoxide; In decane; ethyl acetate; at 20 ℃; for 0.5h; Molecular sieve;

With manganese(III) triacetate dihydrate; at 20 ℃; for 48h;

With triethylamine; at 20 ℃; for 0.5h;
DOI:10.1021/ol302908a

Reference yield:

: 1410840-49-1
methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate

: 1410840-52-6
methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

: 1410840-54-8
methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

Guidance literature:: With sodium tetrahydroborate; cerium(III) chloride heptahydrate; In methanol; at 0 ℃; for 0.333333h; Overall yield = 74%; Overall yield = 280.4 mg; Optical yield = 22.222 %de;
DOI:10.1021/ol302908a

Reference yield:

: 1410840-49-1
methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate

: 1410840-56-0
1,4-trans-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-(methoxymethoxy)cyclohexa-2,5-dienecarboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: cerium(III) chloride heptahydrate; sodium tetrahydroborate / methanol / 0.33 h / 0 °C

2: N-ethyl-N,N-diisopropylamine / dichloromethane / 3 h / 0 - 20 °C

3: lithium hydroxide / tetrahydrofuran; methanol / 12 h / 20 - 50 °C

With sodium tetrahydroborate; cerium(III) chloride heptahydrate; N-ethyl-N,N-diisopropylamine; lithium hydroxide; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ol302908a