methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

Base Information

Chemical Name:methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate
CAS No.:1410840-52-6
Molecular Formula:C₂₅H₃₀O₄Si
Molecular Weight:422.596
Hs Code.:

Synonyms:methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

Suppliers and Price of methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

There total 2 articles about methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1410840-49-1
methyl-1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-oxocyclohexa-2,5-dienecarboxylate

: 1410840-52-6
methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

: 1410840-54-8
methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

Guidance literature:: With sodium tetrahydroborate; cerium(III) chloride heptahydrate; In methanol; at 0 ℃; for 0.333333h; Overall yield = 74%; Overall yield = 280.4 mg; Optical yield = 22.222 %de;
DOI:10.1021/ol302908a

Reference yield:

: 1410840-47-9
methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)cyclohexa-2,5-dienecarboxylate

: 1410840-52-6
methyl 1-(((tert-butyldiphenylsilyl)oxy)methyl)-4-hydroxycyclohexa-2,5-dienecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: tert.-butylhydroperoxide / ethyl acetate; decane / 0.5 h / 20 °C / Molecular sieve

1.2: 48 h / 20 °C

1.3: 0.5 h / 20 °C

2.1: cerium(III) chloride heptahydrate; sodium tetrahydroborate / methanol / 0.33 h / 0 °C

With tert.-butylhydroperoxide; sodium tetrahydroborate; cerium(III) chloride heptahydrate; In methanol; decane; ethyl acetate;
DOI:10.1021/ol302908a