C₃₅H₅₈OSi

Base Information

• Chemical Name: C₃₅H₅₈OSi
• CAS No.: 1313809-07-2
• Molecular Formula: C₃₅H₅₈OSi
• Molecular Weight: 522.93
• Mol file: 1313809-07-2.mol

Synonyms:C₃₅H₅₈OSi

Chemical Property of C₃₅H₅₈OSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₅H₅₈OSi

There total 6 articles about C₃₅H₅₈OSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

C38H66OSi2 (1313809-06-1) → C35H58OSi (1313809-07-2)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; methanol; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1021/ja203536t

Reference yield:

1-bromo-4-iodo-2-methoxybenzene (755027-18-0) → C35H58OSi (1313809-07-2)

Guidance literature:

Multi-step reaction with 5 steps

1: boron tribromide / dichloromethane / -78 - 20 °C / Inert atmosphere

2: potassium carbonate; potassium iodide / N,N-dimethyl-formamide / 24 h / 60 °C / Inert atmosphere

3: piperidine; copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; triphenylphosphine / 8 h / 20 °C / Inert atmosphere

4: piperidine; copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; triphenylphosphine / 12 h / 50 °C / Inert atmosphere

5: potassium carbonate / tetrahydrofuran; methanol / 3 h / 20 °C / Inert atmosphere

With piperidine; copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; boron tribromide; potassium carbonate; triphenylphosphine; potassium iodide; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; 3: Sonogashira coupling / 4: Sonogashira coupling;

DOI:10.1021/ja203536t

Reference yield:

2-bromo-5-iodophenol (932372-99-1) → C35H58OSi (1313809-07-2)

Guidance literature:

Multi-step reaction with 4 steps

1: potassium carbonate; potassium iodide / N,N-dimethyl-formamide / 24 h / 60 °C / Inert atmosphere

2: piperidine; copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; triphenylphosphine / 8 h / 20 °C / Inert atmosphere

3: piperidine; copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; triphenylphosphine / 12 h / 50 °C / Inert atmosphere

4: potassium carbonate / tetrahydrofuran; methanol / 3 h / 20 °C / Inert atmosphere

With piperidine; copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; potassium carbonate; triphenylphosphine; potassium iodide; In tetrahydrofuran; methanol; N,N-dimethyl-formamide; 2: Sonogashira coupling / 3: Sonogashira coupling;

DOI:10.1021/ja203536t

upstream raw materials:

1-bromo-4-iodo-2-methoxybenzene

2-bromo-5-iodophenol

1-bromo-2-hexadecyloxy-4-iodobenzene

C₃₈H₆₆OSi₂

Downstream raw materials:

C₈₈H₁₃₄O₄S₂Si₂