Pd2(μ-CO)Cl2(μ-dppm)2

Base Information

Chemical Name:Pd2(μ-CO)Cl2(μ-dppm)2
CAS No.:64345-32-0
Molecular Formula:C₅₁H₄₄Cl₂OP₄Pd₂
Molecular Weight:1080.55
Hs Code.:

Synonyms:Pd2(μ-CO)Cl2(μ-dppm)2

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Chemical Property of Pd2(μ-CO)Cl2(μ-dppm)2

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Technology Process of Pd2(μ-CO)Cl2(μ-dppm)2

There total 7 articles about Pd2(μ-CO)Cl2(μ-dppm)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 14878-28-5
sodium tetracarbonyl cobaltate

: 64345-29-5
Pd2Cl2(μ-bis(diphenylphosphino)methane)2

: 113109-24-3
{Pd₂Co₂(CO)7(dppm)2}

: 64345-32-0
Pd2(μ-CO)Cl2(μ-dppm)2

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; A filtered soln. of Na{Co(CO)4} in THF was added to a cooled (-78°C) and stirred suspn. of Pd2Cl2(dppm)2 in THF. The react. temp. was raised to 0°C (3h) and then to 20°C (5h).; The mixt. was filtered to remove insol. NaCl and Pd2Cl2(μ-CO)(dppm)2. Addn. of n-hexane gave, after cooling at -20°C, a powder, which was washed with H2O, dried in vac. and recrystd. from CH2Cl2/n-hexane. Elem.anal.;

Reference yield: 66.0%

: 64345-29-5
[Pd2Cl2(μ-bis(diphenylphosphino)methane)2]

: 25875-19-8
K{iron(carbonyl)3nitrosyl}

: 52843-17-1
{(iron(carbonyl)4)2(μ-dppm)}

: 64345-32-0
{(palladium)2(Cl)2(μ-carbonyl)(μ-dppm)2

: 111026-17-6
{(iron(carbonyl)(nitrosyl)2)2(μ-dppm)}

: 111026-19-8
{(palladium)2(μ3-carbonyl)2(iron)2(carbonyl)3(nitrosyl)2(μ-dppm)2

Guidance literature:: In tetrahydrofuran; byproducts: KCl; Addn. of K(Fe(CO)3NO) soln. to a cooled (-78°C, N2) and stirred suspn. of (Pd2Cl2(μ-pddm)) in the dark, warming (0°C, 2 h), color change (orange to deep violet), warming (20°C), color change (dark blue to deep green, 8 h).; Filtn. to remove KCl and (Pd2Cl2(μ-CO)(μ-dppm)2), addn. of n-hexane, cooling (-20°C), filtration, washing with H2O, drying in vac., recrystn. (CH2Cl2/n-hexane), elem. anal.;

Reference yield: 25.3%

: 64345-29-5
[Pd2Cl2(μ-bis(diphenylphosphino)methane)2]

: 13859-41-1
sodium-manganese pentacarbonyl

: 86028-11-7
{(palladium)2(manganese)2(carbonyl)8(μ3-carbonyl)(μ-dppm)2}

: 10170-69-1
dimanganese decacarbonyl

: 37523-60-7
μ-bis(diphenylphosphino)methane-P:P'-octacarbonyldimanganese(Mn-Mn)

: 85688-54-6
{(palladium)(manganese)(Cl)(carbonyl)3(μ-dppm)2}

: 64345-32-0
{(palladium)2(Cl)2(μ-carbonyl)(μ-dppm)2

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; Addn. of filtered Na(Mn(CO)5) soln. to a suspn. of Pd2Cl2(μ-dppm)2 (cooling (-78°C), N2, stirring), no react. until warming to 0°C, slow color change (orange to brown-violet).; Filtn. after 4 h, evapn. in vac., addn. of pentane at -20°C, filtn. of brown powder, dissolving in THF, replacing by freshly distd. CH2Cl2, addn. of n-hexane, cooling (-20°C), elem. anal., column chromy. of filtrate yields other complexes.;