dimesitylchlorogermane

Base Information

• Chemical Name: dimesitylchlorogermane
• CAS No.: 83686-80-0
• Molecular Formula: C₁₈H₂₃ClGe
• Molecular Weight: 347.424
• Mol file: 83686-80-0.mol

Synonyms:dimesitylchlorogermane

Chemical Property of dimesitylchlorogermane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of dimesitylchlorogermane

There total 1 articles about dimesitylchlorogermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

N-chloro-succinimide (128-09-6) + bis(2,4,6-trimethylphenyl)germane (72876-19-8) → dimesitylchlorogermane (83686-80-0)

Guidance literature:

In tetrahydrofuran; soln. of reagents in THF, N2 atm., 23 h, 80°C; evapd., pentane was added, filtered, concd., pptn. by MeOH; recrystd. from pentane; elem. anal.;

Reference yield: 97.0%

dimesitylchlorogermane (83686-80-0) → dimesitylgermanol (114806-86-9)

Guidance literature:

With ammonium hydroxide; In tetrahydrofuran; ammonia; to soln. of germane in THF in Schlenk tube under N2 20% NH4OH was added, stirring for 17 h at 20°C; evapd., ether was added, ether layer was dried under Na2SO4; evapd.;

Reference yield: 52.0%

dimesitylchlorogermane (83686-80-0) + 3,5-di-tert-butyl-o-benzoquinone (3383-21-9) → 3,5-Di-tert-butylcatechol (1020-31-1,122983-47-5,881376-69-8) + dichlorodimesitylgermane (96481-42-4) + 2,2-dimesityl(6,8-di-t-butyl)-4,5-benzo-2-germa-1,3-dioxolane (110577-24-7)

Guidance literature:

In benzene; byproducts: HCl; 12 h at 60 ° C in a sealde tube, concn. under reduced pressure; anal.; 38% starting germane left;

DOI:10.1016/0022-328X(88)80524-2

upstream raw materials:

N-chloro-succinimide

bis(2,4,6-trimethylphenyl)germane

Downstream raw materials:

1,1-bis(2,4,6-trimethylphenyl)-3,4-dimethylgermacyclopent-3-ene

2,2,4,4-tetramesityl-1,3,2,4-dioxadigermetane

2,4,6-trimethyl-N-(phenylmethylene)benzenamine

3,5-Di-tert-butylcatechol