Germane, dichlorobis(2,4,6-trimethylphenyl)-

Base Information

• Chemical Name: Germane, dichlorobis(2,4,6-trimethylphenyl)-
• CAS No.: 96481-42-4
• Molecular Formula: C18H22Cl2Ge
• Molecular Weight: 381.869
• DSSTox Substance ID: DTXSID40452367
• Nikkaji Number: J1.611.876A
• Wikidata: Q82272955
• Mol file: 96481-42-4.mol

Synonyms:Germane, dichlorobis(2,4,6-trimethylphenyl)-;96481-42-4;Dimesityldichlorogermane;DTXSID40452367

Chemical Property of Germane, dichlorobis(2,4,6-trimethylphenyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 382.0310338
• Heavy Atom Count: 21
• Complexity: 301

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)[Ge](C2=C(C=C(C=C2C)C)C)(Cl)Cl)C

Technology Process of Germane, dichlorobis(2,4,6-trimethylphenyl)-

There total 8 articles about Germane, dichlorobis(2,4,6-trimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

bis(2,4,6-trimethylphenyl)germane (72876-19-8) → dichlorodimesitylgermane (96481-42-4)

Guidance literature:

With tetrachloromethane; dibenzoyl peroxide; In tetrachloromethane; dry/inert atmosphere; refluxing (6 h); evapn.;

DOI:10.1080/00945719608004362

Reference yield: 76.0%

1,2-dichlorotetramesityldigermane (100418-04-0) + 3,5-di-tert-butyl-o-benzoquinone (3383-21-9) → dichlorodimesitylgermane (96481-42-4) + 2,2-dimesityl(6,8-di-t-butyl)-4,5-benzo-2-germa-1,3-dioxolane (110577-24-7)

Guidance literature:

In benzene-d6; Irradiation (UV/VIS); (high vacuum system), 4h at 30°C, 254 nm; detected by NMR, GC/MS;

DOI:10.1016/0022-328X(86)80434-X

Reference yield: 54.0%

germaniumtetrachloride (10038-98-9) + 2-mesitylmagnesium bromide (2633-66-1) → dichlorodimesitylgermane (96481-42-4)

Guidance literature:

In diethyl ether; dry/inert atmosphere; stirring (6 h); aq. HCl addn., ether layer evapn., hexane trituration, drying;

DOI:10.1080/00945719608004362

upstream raw materials:

dimesitylgerma(2,4,6-tri-tert-butylphenyl)phosphene

tetrachloromethane

germaniumtetrachloride

2-mesitylmagnesium bromide

Downstream raw materials:

dimesitylbis(trimethylsilyl)germane

2,2-dimesityl(6,8-di-t-butyl)-4,5-benzo-2-germa-1,3-dioxolane

hexamesitylcyclotrigermane

dimesityldimethoxygermane