2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dioxadigermetane

Base Information

Chemical Name:2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dioxadigermetane
CAS No.:132775-06-5
Molecular Formula:C₃₆H₄₄Ge₂O₂
Molecular Weight:653.924
Hs Code.:
DSSTox Substance ID:DTXSID20587242
Nikkaji Number:J1.670.033I
Wikidata:Q82479619

Synonyms:132775-06-5;2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dioxadigermetane;DTXSID20587242

Suppliers and Price of 2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dioxadigermetane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dioxadigermetane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:654.1773842
Heavy Atom Count:40
Complexity:687

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C(=C1)C)[Ge]2(O[Ge](O2)(C3=C(C=C(C=C3C)C)C)C4=C(C=C(C=C4C)C)C)C5=C(C=C(C=C5C)C)C)C

Technology Process of 2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dioxadigermetane

There total 16 articles about 2,2,4,4-Tetrakis(2,4,6-trimethylphenyl)-1,3,2,4-dioxadigermetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 108946-03-8
bis(2,4,6-trimethylphenyl)fluorenylidenegermene

: 586-96-9
Nitrosobenzene

: 132775-06-5
2,2,4,4-tetramesityl-1,3,2,4-dioxadigermetane

Guidance literature:: In diethyl ether; benzene; byproducts: C6H5NC(C12H8); (N2 or Ar); adding a soln. of nitrosobenzene in benzene to a soln. of Ge-compound cooled to -78°C; warmed to room temp. for 2 h; evapd. in vacuo; recrystd. from pentane;
DOI:10.1021/om00050a054

Reference yield: 37.0%

: 617-86-7
triethylsilane

: 107824-84-0
hexamesitylcyclotrigermane

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 132775-06-5
2,2,4,4-tetramesityl-1,3,2,4-dioxadigermetane

: 400717-04-6
2,2,4,4,5,5-hexamesityl-2,4,5-trigermadioxolane

: 400717-03-5
tetramesityldigermadioxirane

: 400717-05-7
(triethylsiloxydimesetyl)germanol

Guidance literature:: In toluene; Irradiation (UV/VIS); (Ar); dissolving of Et3SiH and Ge3(C6H2Me3)6 in toluene, irradn. (350 nm) at -70°C for 18 h; addn. via cannula of soln. m-chloroperbenzoic acid in dried degassed toluene; washing with satd. Na2SO3 and then with water, removal of solvent under vac., sepn. by chromy. (90/10 CH2Cl2-hexane);
DOI:10.1016/S0022-328X(01)01040-3

Reference yield: 14.0%

: 617-86-7
triethylsilane

: 107824-84-0
hexamesitylcyclotrigermane

: 80937-33-3
oxygen

: 132775-06-5
2,2,4,4-tetramesityl-1,3,2,4-dioxadigermetane

: 400717-04-6
2,2,4,4,5,5-hexamesityl-2,4,5-trigermadioxolane

: 144435-57-4
dimesityl(triethylsilyl)germane

: 400717-03-5
tetramesityldigermadioxirane

: 400717-02-4
3,3,4,4-tetramesityl-3,4-digermadioxetane

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); dissolving of Et3SiH and Ge3(C6H2Me3)6 in THF, irradn. (350 nm) at -70°C for 16 h under the ambient atmosphere; removal of solvent under vac., addn. of C6D6; crystn., filtration, sepn.by chromy. (CH2Cl2);
DOI:10.1016/S0022-328X(01)01040-3