bis(3-methoxyphenyl)iodonium triflate

Base Information

• Chemical Name: bis(3-methoxyphenyl)iodonium triflate
• CAS No.: 141339-53-9
• Molecular Formula: CF₃O₃S*C₁₄H₁₄IO₂
• Molecular Weight: 490.239
• Mol file: 141339-53-9.mol

Synonyms:bis(3-methoxyphenyl)iodonium triflate

Chemical Property of bis(3-methoxyphenyl)iodonium triflate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(3-methoxyphenyl)iodonium triflate

There total 3 articles about bis(3-methoxyphenyl)iodonium triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

tributyl(3-methoxyphenyl)stannane (122439-11-6) + di(cyano)iodonium triflate (141339-50-6) → bis(3-methoxyphenyl)iodonium triflate (141339-53-9)

Guidance literature:

In dichloromethane; at -40 - 20 ℃;

DOI:10.1016/S0040-4039(00)91636-8

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + 3-methoxy-1-iodobenzene (766-85-8) + methoxybenzene (100-66-3) → bis(3-methoxyphenyl)iodonium triflate (141339-53-9)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃;

DOI:10.1021/jo501467v

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + 3-methoxy-1-iodobenzene (766-85-8) + 3-methoxyphenylboronic acid (10365-98-7,1107579-37-2) → bis(3-methoxyphenyl)iodonium triflate (141339-53-9)

Guidance literature:

3-methoxy-1-iodobenzene; With boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 1h;

3-methoxyphenylboronic acid; In dichloromethane; at 0 - 20 ℃; for 0.5h;

trifluorormethanesulfonic acid; In dichloromethane; for 0.25h;

DOI:10.1021/acs.orglett.1c03016

upstream raw materials:

tributyl(3-methoxyphenyl)stannane

di(cyano)iodonium triflate

trifluorormethanesulfonic acid

3-methoxy-1-iodobenzene

Downstream raw materials:

2-(3-methoxyphenyl)[1,4]naphthoquinone

1-methoxy-3-((4-methoxyphenyl)sulfonyl)benzene