122439-11-6

Basic information

• Product Name: Tributyl(3-methoxyphenyl)stannane
• Synonyms: Tributyl(3-methoxyphenyl)stannane
• CAS NO: 122439-11-6
• Molecular Formula: C₁₉H₃₄OSn
• Molecular Weight: 397.18266
• Mol File: 122439-11-6.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Tributyl(3-methoxyphenyl)stannane(CAS DataBase Reference)
• NIST Chemistry Reference: Tributyl(3-methoxyphenyl)stannane(122439-11-6)
• EPA Substance Registry System: Tributyl(3-methoxyphenyl)stannane(122439-11-6)

Safety Data

• Hazardous Substances Data: 122439-11-6(Hazardous Substances Data)

Upstream product

• 10130-74-2 m-Methoxybenzenesulfonyl chloride 
• 813-19-4 bis(tri-n-butyltin) 
• 150-19-6 O-methylresorcine 
• 2398-37-0 3-methoxyphenyl bromide 
• 1461-22-9 tributyltin chloride 

Downstream Products

• 155061-61-3 3'-methoxy-biphenyl-4-carboxylic acid ethyl ester 
• 352032-26-9 3-methoxy-3'-(trifluoromethyl)-1,1'-biphenyl 
• 149452-90-4 3-methoxyphenyl 4-methylphenyl sulfone 
• 122439-14-9 4-[(3-methoxyphenyl)methyl]morpholine 
• 27331-43-7 1-(3-methoxybiphenyl)naphthalene 
• 32363-45-4 (4-chlorophenyl)(3-methoxyphenyl)methanone 
• 75731-44-1 4,3'-dimethoxybenzophenone 
• 6136-67-0 3-methoxybenzophenone 
• 2845-89-8 1-chloro-3-methoxy-benzene 
• 1139881-22-3 anisole 
• 1139881-20-1 anisole 

Relevant articles and documents

Development of oxathiino[6,5-b]pyridine 2,2-dioxide derivatives as selective inhibitors of tumor-related carbonic anhydrases IX and XII

Oxathiino[6,5-b]pyridine 2,2-dioxides are identified as a new class of isoform-selective nanomolar inhibitors of tumor associated human carbonic anhydrases (hCA) IX and XII. At the same time they do not inhibit or poorly inhibit cytosolic isoforms hCA I and II. Oxathiino[6,5-b]pyridine 2,2-dioxides exhibited good antiproliferative properties on tumor cell lines MCF-7 (Human breast adenocarcinoma), A549 (human lung (alveolar) adenocarcinoma) and HeLa (epithelioid cervix carcinoma).

Gold(i)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes

Gold(i)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes are described. This redox neutral strategy offers an efficient approach to diverse biaryls, vinyl arenes and arylacetylenes. Monitoring the reaction with NMR and ESI-MS provided strong evidence for the in situ formation of Ph3PAuIR (R = aryl, vinyl and alkynyl) species which is crucial for the activation of aryldiazonium salts.

Ni-Catalyzed Stannylation of Aryl Esters via C?O Bond Cleavage

A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents via Csp2 ?O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C?heteroatom bond formations.