Cerium triacetate

Base Information

• Chemical Name: Cerium triacetate
• CAS No.: 537-00-8
• Deprecated CAS: 16922-01-3,874527-03-4
• Molecular Formula: 4C₂H₃O₂*Ce
• Molecular Weight: 376.298
• European Community (EC) Number: 208-654-0
• UNII: YYB5291R2H
• DSSTox Substance ID: DTXSID2027179
• Nikkaji Number: J55.407C
• Wikipedia: Cerium(III)_acetate
• Wikidata: Q15730268
• Mol file: 537-00-8.mol

Synonyms:Cerium triacetate;537-00-8;CERIUM ACETATE;Cerous acetate;Cerium(III) acetate;Cerium(3+) acetate;cerium(3+);triacetate;Acetic acid, cerium(3+) salt;Triacetic acid cerium(III) salt;EINECS 208-654-0;Acetic acid, cerium(3+) salt (3:1);cerium(III)acetate;C6H12O6.Ce.3/2H2O;C6-H12-O6.Ce.3/2H2-O;Acetic acid, cerium(3) salt, sesquihydrate;UNII-YYB5291R2H;Acetic Acid Cerium(III) Salt;YYB5291R2H;C2H4O2.1/3Ce;DTXSID2027179;Acetic acid, cerium(3++) salt;VGBWDOLBWVJTRZ-UHFFFAOYSA-K;3(C2-H3-O2).Ce;AKOS030228513;J55.407C;LS-52771;Cetic acid, cerium(3+) salt (8CI,9CI);C2974;CERIUM(III)ACETATESESQUIHYDRATE,99.9%(REO);Q15730268;Cerium (III) acetate sesquihydrate, 99.9%, trace metals grade;Cerium (III) acetate sesquihydrate, 99.99%, trace metals grade

Chemical Property of Cerium triacetate

Chemical Property:

• Appearance/Colour: white to yellow powder
• Vapor Pressure: 0.01Pa at 180℃
• Melting Point: 308 °C
• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 120.39000
• LogP: -3.73140
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 316.94536
• Heavy Atom Count: 13
• Complexity: 25.5

Purity/Quality:

99.9% ^*data from raw suppliers

Cerium(III) acetate sesquihydrate, REacton?, 99.99% (REO) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Ce+3]
• Uses: Cerium Acetate, is applied as an alternative material for auto catalyst manufacturing and also for some special polishing powder. In glass industry, it is considered to be the most efficient glass polishing agent for precision optical polishing. It is added to the dominant catalyst for the production of styrene from methylbenzene to improve styrene formation. It is used in FCC catalysts containing zeolites to provide both catalytic reactivity in the reactor and thermal stability in the regenerator.

Technology Process of Cerium triacetate

There total 10 articles about Cerium triacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cerium chloride (7790-86-5,15785-07-6) → cerium(III) acetate (537-00-8,19475-87-7,57023-24-2)

Guidance literature:

With acetic acid; In acetic acid; byproducts: HCl; heating under reflux; filtered, washed several times with dry acetic acid, dried under reduced pressure at 60°C;

DOI:10.1016/0022-1902(63)80010-X

Reference yield:

cerous nitrate → cerium(III) acetate (537-00-8,19475-87-7,57023-24-2)

Guidance literature:

With acetic anhydride; In acetic anhydride; acetic acid; the metal nitrate was refluxed with an excess (60:40) of a mixt. of acetic anhydride and acetic acid; the react. is highly exothermic;;

Reference yield:

cerium (III) carbonate + acetic acid (64-19-7,77671-22-8) → cerium(III) acetate (537-00-8,19475-87-7,57023-24-2)

Guidance literature:

Heating;

DOI:10.1021/cs400003n

upstream raw materials:

potassium acetate

cerium(III) acetate

acetic anhydride

cerium chloride

Downstream raw materials:

acetic acid ; cerium (IV)-acetate

Refernces

• 1、 Singh, Sukhjinder,Verma, Maninder,Verma, Rajendar D.. "Some New Chlorosulphates". . p. 1038 - 1040. Retrieved 2007/10/02.